Synthesis, structure and fluorescent properties of 2-(1H-benzoimidazol-2-yl)quinolin-8-ol ligands and their zinc complexes
文献类型:期刊论文
作者 | Xia, Juanjuan2; Zhou, Zihong3,4; Li, Wen1; Zhang, Hu-Qin2; Redshaw, Carl5; Sun, Wen-Hua3,4![]() |
刊名 | INORGANICA CHIMICA ACTA
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出版日期 | 2013 |
卷号 | 394页码:569-575 |
关键词 | 2-(1h-benzoimidazol-2-yl)Quinolin-8-ol Zinc Complex Molecular Structure Uv-absorption Spectra Fluorescence |
ISSN号 | 0020-1693 |
DOI | 10.1016/j.ica.2012.09.012 |
英文摘要 | A series of 2-(1H-benzoimidazol-2-yl)quinolin-8-ol ligands (L1-L5) and their Zn(II) complexes (C1-C6) were synthesized and characterized by spectroscopic and elemental analyses. The molecular structures of C1 and C6 were confirmed by single-crystal X-ray diffraction; the zinc centre in complex C1 was found to be five-coordination as a distorted tetrahedral geometry, meanwhile the zinc centre in complex C6 adopted as six-coordination as a octahedral geometry. UV-Vis absorption and fluorescent spectra in different solvent were measured, and the substituent effects as well as those of the solvents on the luminescent properties were analyzed. The maximum emission wavelengths of all complexes were generally blue-shifted compared to the free ligands. (C) 2012 Elsevier B. V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000311492900076 |
出版者 | ELSEVIER SCIENCE SA |
源URL | [http://ir.iccas.ac.cn/handle/121111/54525] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Li, Wen |
作者单位 | 1.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China 2.Xi An Jiao Tong Univ, Key Lab Biomed Informat Engn, Minist Educ, Sch Life Sci & Technol, Xian 710049, Peoples R China 3.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 4.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 5.Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England |
推荐引用方式 GB/T 7714 | Xia, Juanjuan,Zhou, Zihong,Li, Wen,et al. Synthesis, structure and fluorescent properties of 2-(1H-benzoimidazol-2-yl)quinolin-8-ol ligands and their zinc complexes[J]. INORGANICA CHIMICA ACTA,2013,394:569-575. |
APA | Xia, Juanjuan,Zhou, Zihong,Li, Wen,Zhang, Hu-Qin,Redshaw, Carl,&Sun, Wen-Hua.(2013).Synthesis, structure and fluorescent properties of 2-(1H-benzoimidazol-2-yl)quinolin-8-ol ligands and their zinc complexes.INORGANICA CHIMICA ACTA,394,569-575. |
MLA | Xia, Juanjuan,et al."Synthesis, structure and fluorescent properties of 2-(1H-benzoimidazol-2-yl)quinolin-8-ol ligands and their zinc complexes".INORGANICA CHIMICA ACTA 394(2013):569-575. |
入库方式: OAI收割
来源:化学研究所
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