中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis, structure and fluorescent properties of 2-(1H-benzoimidazol-2-yl)quinolin-8-ol ligands and their zinc complexes

文献类型:期刊论文

作者Xia, Juanjuan2; Zhou, Zihong3,4; Li, Wen1; Zhang, Hu-Qin2; Redshaw, Carl5; Sun, Wen-Hua3,4
刊名INORGANICA CHIMICA ACTA
出版日期2013
卷号394页码:569-575
关键词2-(1h-benzoimidazol-2-yl)Quinolin-8-ol Zinc Complex Molecular Structure Uv-absorption Spectra Fluorescence
ISSN号0020-1693
DOI10.1016/j.ica.2012.09.012
英文摘要A series of 2-(1H-benzoimidazol-2-yl)quinolin-8-ol ligands (L1-L5) and their Zn(II) complexes (C1-C6) were synthesized and characterized by spectroscopic and elemental analyses. The molecular structures of C1 and C6 were confirmed by single-crystal X-ray diffraction; the zinc centre in complex C1 was found to be five-coordination as a distorted tetrahedral geometry, meanwhile the zinc centre in complex C6 adopted as six-coordination as a octahedral geometry. UV-Vis absorption and fluorescent spectra in different solvent were measured, and the substituent effects as well as those of the solvents on the luminescent properties were analyzed. The maximum emission wavelengths of all complexes were generally blue-shifted compared to the free ligands. (C) 2012 Elsevier B. V. All rights reserved.
语种英语
WOS记录号WOS:000311492900076
出版者ELSEVIER SCIENCE SA
源URL[http://ir.iccas.ac.cn/handle/121111/54525]  
专题中国科学院化学研究所
通讯作者Li, Wen
作者单位1.Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China
2.Xi An Jiao Tong Univ, Key Lab Biomed Informat Engn, Minist Educ, Sch Life Sci & Technol, Xian 710049, Peoples R China
3.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
5.Univ E Anglia, Sch Chem, Norwich NR4 7TJ, Norfolk, England
推荐引用方式
GB/T 7714
Xia, Juanjuan,Zhou, Zihong,Li, Wen,et al. Synthesis, structure and fluorescent properties of 2-(1H-benzoimidazol-2-yl)quinolin-8-ol ligands and their zinc complexes[J]. INORGANICA CHIMICA ACTA,2013,394:569-575.
APA Xia, Juanjuan,Zhou, Zihong,Li, Wen,Zhang, Hu-Qin,Redshaw, Carl,&Sun, Wen-Hua.(2013).Synthesis, structure and fluorescent properties of 2-(1H-benzoimidazol-2-yl)quinolin-8-ol ligands and their zinc complexes.INORGANICA CHIMICA ACTA,394,569-575.
MLA Xia, Juanjuan,et al."Synthesis, structure and fluorescent properties of 2-(1H-benzoimidazol-2-yl)quinolin-8-ol ligands and their zinc complexes".INORGANICA CHIMICA ACTA 394(2013):569-575.

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来源:化学研究所

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