2-(1-Aryliminoethyl)cycloheptapyridylpalladium complexes: Synthesis, characterization and the use in the Heck-reaction
文献类型：期刊论文
| 作者 | Ye, Bin1,2,3; Wang, Lin2,3; Hu, Xinquan1; Redshaw, Carl4; Sun, Wen-Hua2,3
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| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2013-10-01 |
| 卷号 | 407页码:281-288 |
| 关键词 | 2-(1-aryliminoethyl)Cycloheptapyridine Palladium Complex Molecular Structure Heck Reaction |
| ISSN号 | 0020-1693 |
| DOI | 10.1016/j.ica.2013.08.008 |
| 英文摘要 | A series of 2-(1-aryliminoethyl)cycloheptapyridine derivatives (L1-L7) were prepared in good yield by the condensation reaction of 2-acetylcycloheptapyridine with various anilines, and then reacted with PdCl2(CH3CN)(2) in dichloromethane to form the respective palladium(II) complexes (C1-C7). All organic and palladium compounds were characterized by FT-IR and NMR spectroscopy, as well as by elemental analysis. The molecular structures of the complexes C4, C5 and C7 were determined by single crystal X-ray diffraction studies and revealed distorted square geometries at each palladium center via the coordination of two nitrogen atoms and two chlorides. All palladium complexes exhibited good activity in the Heck cross-coupling reaction between bromoarenes and styrene, and the catalytic systems possessed high thermal stability. (C) 2013 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000325471600040 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54535]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Hu, Xinquan |
| 作者单位 | 1.Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou 310014, Zhejiang, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 4.Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England |
| 推荐引用方式 GB/T 7714 | Ye, Bin,Wang, Lin,Hu, Xinquan,et al. 2-(1-Aryliminoethyl)cycloheptapyridylpalladium complexes: Synthesis, characterization and the use in the Heck-reaction[J]. INORGANICA CHIMICA ACTA,2013,407:281-288. |
| APA | Ye, Bin,Wang, Lin,Hu, Xinquan,Redshaw, Carl,&Sun, Wen-Hua.(2013).2-(1-Aryliminoethyl)cycloheptapyridylpalladium complexes: Synthesis, characterization and the use in the Heck-reaction.INORGANICA CHIMICA ACTA,407,281-288. |
| MLA | Ye, Bin,et al."2-(1-Aryliminoethyl)cycloheptapyridylpalladium complexes: Synthesis, characterization and the use in the Heck-reaction".INORGANICA CHIMICA ACTA 407(2013):281-288. |
入库方式： OAI收割
来源：化学研究所
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