Electron Spin Manipulation via Encaged Cluster: Differing Anion Radicals of Y-2@C-82-C-s, Y2C2@C-82-C-s, and Sc2C2@C-82-C-s
文献类型：期刊论文
| 作者 | Ma, Yihan1; Wang, Taishan1; Wu, Jingyi2; Feng, Yongqiang1; Li, Hui1; Jiang, Li1; Shu, Chunying1; Wang, Chunru1 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY LETTERS
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| 出版日期 | 2013-02-07 |
| 卷号 | 4期号:3页码:464-467 |
| ISSN号 | 1948-7185 |
| DOI | 10.1021/jz3020666 |
| 英文摘要 | Endohedral metallofullerene species with controllable electron spin have attracted increasing attention along with their potential application in quantum information processing. In this paper, we report the electron spin manipulation via encage cluster through comparative studies on the anion radicals of metallofullerene Y-2@C-82-C-s, Y2C2@C-82-C-s, and Sc2C2@C-82-C-s. Although these three radical species have the same parent fullerene cage, we found that the unpaired spin characteristics as well as metal-spin couplings of them can be greatly affected by endohedral clusters. Furthermore, based on theoretical calculations, it was revealed that the encaged clusters can affect the electronic population of pristine endohedral metallofullerenes and eventually manipulate the spin distribution of their corresponding anion radicals. Our findings are referential to the spin coherence in information processing due to the variable paramagnetism of these metallofullerene radicals. |
| 语种 | 英语 |
| WOS记录号 | WOS:000314907500022 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54583]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Taishan |
| 作者单位 | 1.Inst Chem, Beijing Natl Lab Mol Sci, Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Inst High Energy Phys, Lab Nucl Anal Tech, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Yihan,Wang, Taishan,Wu, Jingyi,et al. Electron Spin Manipulation via Encaged Cluster: Differing Anion Radicals of Y-2@C-82-C-s, Y2C2@C-82-C-s, and Sc2C2@C-82-C-s[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS,2013,4(3):464-467. |
| APA | Ma, Yihan.,Wang, Taishan.,Wu, Jingyi.,Feng, Yongqiang.,Li, Hui.,...&Wang, Chunru.(2013).Electron Spin Manipulation via Encaged Cluster: Differing Anion Radicals of Y-2@C-82-C-s, Y2C2@C-82-C-s, and Sc2C2@C-82-C-s.JOURNAL OF PHYSICAL CHEMISTRY LETTERS,4(3),464-467. |
| MLA | Ma, Yihan,et al."Electron Spin Manipulation via Encaged Cluster: Differing Anion Radicals of Y-2@C-82-C-s, Y2C2@C-82-C-s, and Sc2C2@C-82-C-s".JOURNAL OF PHYSICAL CHEMISTRY LETTERS 4.3(2013):464-467. |
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来源：化学研究所
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