中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Controlled radical emulsion polymerization of polystyrene

文献类型:期刊论文

作者Jin, Xin1,2; Kang, Hongliang1; Liu, Ruigang1; Huang, Yong1,3
刊名COLLOID AND POLYMER SCIENCE
出版日期2013-10-01
卷号291期号:10页码:2481-2485
关键词Emulsion Polymerization Controlled Free-radical Polymerization (Crp) Polystyrene Latex Particle
ISSN号0303-402X
DOI10.1007/s00396-013-2998-6
英文摘要In this paper, a new water-soluble initiator system, 2-bromopropane/CuSO4/sodium ascorbate, was used as the initiator for emulsion polymerization. Radical emulsion polymerization of styrene was successfully carried out at 80 A degrees C by using sodium dodecylbenzenesulfonate as the emulsifier. The 2-bromopropane/CuSO4/sodium ascorbate-initiated emulsion polymerization shows the controlled free-radical polymerization features with linear growth of molecular weight. Polystyrene with a relatively high molecular weight and a narrow molecular weight distribution can be synthesized by this method. On the other hand, stable polystyrene latex can be obtained, and the size of the polystyrene latex increased with the increase in monomer conversion.
语种英语
WOS记录号WOS:000324559200024
出版者SPRINGER
源URL[http://ir.iccas.ac.cn/handle/121111/54599]  
专题中国科学院化学研究所
通讯作者Liu, Ruigang
作者单位1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
3.Chinese Acad Sci, Tech Inst Phys & Chem, Nat Res Ctr Engn Plast, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Jin, Xin,Kang, Hongliang,Liu, Ruigang,et al. Controlled radical emulsion polymerization of polystyrene[J]. COLLOID AND POLYMER SCIENCE,2013,291(10):2481-2485.
APA Jin, Xin,Kang, Hongliang,Liu, Ruigang,&Huang, Yong.(2013).Controlled radical emulsion polymerization of polystyrene.COLLOID AND POLYMER SCIENCE,291(10),2481-2485.
MLA Jin, Xin,et al."Controlled radical emulsion polymerization of polystyrene".COLLOID AND POLYMER SCIENCE 291.10(2013):2481-2485.

入库方式: OAI收割

来源:化学研究所

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