The Utilization of Isolation Chromophore in an "A3+B2" Type Second-Order Nonlinear Optical Hyperbranched Polymer
文献类型：期刊论文
| 作者 | Wu, Wenbo1; Ye, Cheng2; Qin, Jingui1; Li, Zhen1 |
| 刊名 | MACROMOLECULAR RAPID COMMUNICATIONS
 |
| 出版日期 | 2013-07-12 |
| 卷号 | 34期号:13页码:1072-1079 |
| 关键词 | Dendritic Strucutures Hyperbranched Polymers Isolation Chromophores Nonlinear Optics |
| ISSN号 | 1022-1336 |
| DOI | 10.1002/marc.201300226 |
| 英文摘要 | In this paper, a new nonlinear optical (NLO) hyperbranched polymer P1 is designed and synthesized successfully through one-pot A3+B2 approach via a simple Sonogashira coupling reaction, in which isolation chromophore is introduced to improve its comprehensive performance such as NLO activity, optical transparency, and stability. For comparison, its analogs, P2 and P3, just containing one type of chromophore, are also prepared. Although P1 cannot be well poled under our test conditions, its NLO coefficient is still much higher than its analogs P2, P3, and the linear polyaryleneethynylene P4, which also contains isolation chromophore, indicating the advantages of isolation chromophore and the three-dimensional (3D) spatial isolation from the highly branched structure in the NLO field. |
| 语种 | 英语 |
| WOS记录号 | WOS:000325869300006 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54633]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Zhen |
| 作者单位 | 1.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Wenbo,Ye, Cheng,Qin, Jingui,et al. The Utilization of Isolation Chromophore in an "A3+B2" Type Second-Order Nonlinear Optical Hyperbranched Polymer[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2013,34(13):1072-1079. |
| APA | Wu, Wenbo,Ye, Cheng,Qin, Jingui,&Li, Zhen.(2013).The Utilization of Isolation Chromophore in an "A3+B2" Type Second-Order Nonlinear Optical Hyperbranched Polymer.MACROMOLECULAR RAPID COMMUNICATIONS,34(13),1072-1079. |
| MLA | Wu, Wenbo,et al."The Utilization of Isolation Chromophore in an "A3+B2" Type Second-Order Nonlinear Optical Hyperbranched Polymer".MACROMOLECULAR RAPID COMMUNICATIONS 34.13(2013):1072-1079. |
入库方式： OAI收割
来源：化学研究所
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