Synthesis, characterization and ethylene polymerization behavior of binuclear iron complexes bearing N,N '-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines
文献类型：期刊论文
| 作者 | Xing, Qifeng1,2; Zhao, Tong1,2; Qiao, Yusen1,2; Wang, Lin1,2; Redshaw, Carl4; Sun, Wen-Hua1,2,3
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| 刊名 | RSC ADVANCES
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| 出版日期 | 2013 |
| 卷号 | 3期号:48页码:26184-26193 |
| ISSN号 | 2046-2069 |
| DOI | 10.1039/c3ra42631a |
| 英文摘要 | A series of N,N'-bis(1-(6-(1-(arylimino)ethyl)pyridin-2-yl)ethylidene)benzidines and the bi-metallic iron complexes thereof have been synthesized and fully characterized. All iron complexes, when activated by MAO or MMAO, exhibited high activities of up to 1.3 x 10(7) g mol(-1) (Fe) h(-1) for the polymerization of ethylene. On comparison with their mononuclear counterparts, such bi-metallic complexes not only retain a relatively high activity at elevated temperatures (up to 70 degrees C), but also exhibit increased lifetimes. The polyethylenes obtained were characterized by GPC, DSC and high temperature NMR spectroscopy, which indicated multimodal and highly linear features. |
| 语种 | 英语 |
| WOS记录号 | WOS:000327261700096 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54639]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Engn Plast, Inst Chem, Beijing 100190, Peoples R China 2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 4.Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England |
| 推荐引用方式 GB/T 7714 | Xing, Qifeng,Zhao, Tong,Qiao, Yusen,et al. Synthesis, characterization and ethylene polymerization behavior of binuclear iron complexes bearing N,N '-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines[J]. RSC ADVANCES,2013,3(48):26184-26193. |
| APA | Xing, Qifeng,Zhao, Tong,Qiao, Yusen,Wang, Lin,Redshaw, Carl,&Sun, Wen-Hua.(2013).Synthesis, characterization and ethylene polymerization behavior of binuclear iron complexes bearing N,N '-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines.RSC ADVANCES,3(48),26184-26193. |
| MLA | Xing, Qifeng,et al."Synthesis, characterization and ethylene polymerization behavior of binuclear iron complexes bearing N,N '-bis(1-(6-(1-(arylimino)ethyl) pyridin-2-yl)ethylidene)benzidines".RSC ADVANCES 3.48(2013):26184-26193. |
入库方式： OAI收割
来源：化学研究所
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