Surface Tectonics of Nanoporous Networks of Melamine-Capped Molecular Building Blocks formed through Interface Schiff-Base Reactions
文献类型：期刊论文
| 作者 | Liu, Xuan-He1,2,3; Wang, Dong1,2; Wan, Li-Jun1,2 |
| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2013-10-01 |
| 卷号 | 8期号:10页码:2466-2470 |
| 关键词 | Interfaces Nanostructures Porous Materials Scanning Probe Microscopy Self-assembly |
| ISSN号 | 1861-4728 |
| DOI | 10.1002/asia.201300546 |
| 英文摘要 | Control over the assembly of molecules on a surface is of great importance for the fabrication of molecule-based miniature devices. Melamine (MA) and molecules with terminal MA units are promising candidates for supramolecular interfacial packing patterning, owing to their multiple hydrogen-bonding sites. Herein, we report the formation of self-assembled structures of MA-capped molecules through a simple on-surface synthetic route. MA terminal groups were successfully fabricated onto rigid molecular cores with 2-fold and 3-fold symmetry through interfacial Schiff-base reactions between MA and aldehyde groups. Sub-molecular scanning tunneling microscopy (STM) imaging of the resultant adlayer revealed the formation of nanoporous networks. Detailed structural analysis indicated that strong hydrogen-bonding interactions between the MA groups persistently drove the formation of nanoporous networks. Herein, we demonstrate that functional groups with strong hydrogen-bond-formation ability are promising building blocks for the guided assembly of nanoporous networks and other hierarchical 2D assemblies. |
| 语种 | 英语 |
| WOS记录号 | WOS:000324748600027 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54707]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Dong |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 2.Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100490, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xuan-He,Wang, Dong,Wan, Li-Jun. Surface Tectonics of Nanoporous Networks of Melamine-Capped Molecular Building Blocks formed through Interface Schiff-Base Reactions[J]. CHEMISTRY-AN ASIAN JOURNAL,2013,8(10):2466-2470. |
| APA | Liu, Xuan-He,Wang, Dong,&Wan, Li-Jun.(2013).Surface Tectonics of Nanoporous Networks of Melamine-Capped Molecular Building Blocks formed through Interface Schiff-Base Reactions.CHEMISTRY-AN ASIAN JOURNAL,8(10),2466-2470. |
| MLA | Liu, Xuan-He,et al."Surface Tectonics of Nanoporous Networks of Melamine-Capped Molecular Building Blocks formed through Interface Schiff-Base Reactions".CHEMISTRY-AN ASIAN JOURNAL 8.10(2013):2466-2470. |
入库方式： OAI收割
来源：化学研究所
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