Two-dimensional self-assemblies of telechelic organic compounds: structure and surface host-guest chemistry
文献类型:期刊论文
作者 | Yan, Hui-Juan; Liu, Jia; Wang, Dong1; Wan, Li-Jun |
刊名 | PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES
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出版日期 | 2013-10-13 |
卷号 | 371期号:2000 |
关键词 | Surface Molecular Engineering Self-assembly Telechelic Molecules Scanning Tunnelling Microscopy Host-guest Chemistry |
ISSN号 | 1364-503X |
DOI | 10.1098/rsta.2012.0302 |
英文摘要 | Guiding the self-assembly of different types of functional molecules into well-defined structures on surfaces is beneficial for both fundamental surface and interface study and emerging application fields, especially molecular and organic electronics. This review focuses on understanding the two-dimensional self-assembly process of telechelic organics, which feature alkoxylene chains terminated with carboxyl groups. With the combined flexibility of alkyl chains and directionality of carboxyl groups, telechelic organics show unique assembly behaviour on two-dimensional surfaces. By increasing the length of the alkoxylene chains, the cavities in the nanoporous networks of telechelic trimesic acid (1,3,5-benzene tricarboxylic acid) derivatives change from hexagonal cavities to irregular cavities on a highly oriented pyrolytic graphite surface. The nanoporous networks provide a flexible host template for host-guest supramolecular chemistry because the cavities framed by the flexible alkoxylene chains can be changed in accordance with the sizes/shapes of the guest molecules. Furthermore, the terminal carboxylic group can form a hydrogen bond with another hydrogen bond partner, leading to multi-component structural motifs and hierarchical assemblies. The unique assembly behaviour of telechelic organics makes them promising structures as important building blocks for the design and construction of complex self-assembled nanoarchitectures. |
语种 | 英语 |
WOS记录号 | WOS:000330311400001 |
出版者 | ROYAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/54731] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wang, Dong |
作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China 2.Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Yan, Hui-Juan,Liu, Jia,Wang, Dong,et al. Two-dimensional self-assemblies of telechelic organic compounds: structure and surface host-guest chemistry[J]. PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES,2013,371(2000). |
APA | Yan, Hui-Juan,Liu, Jia,Wang, Dong,&Wan, Li-Jun.(2013).Two-dimensional self-assemblies of telechelic organic compounds: structure and surface host-guest chemistry.PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES,371(2000). |
MLA | Yan, Hui-Juan,et al."Two-dimensional self-assemblies of telechelic organic compounds: structure and surface host-guest chemistry".PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES 371.2000(2013). |
入库方式: OAI收割
来源:化学研究所
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