Oligothiophene-Bridged Bis(arylene ethynylene) Small Molecules for Solution-Processible Organic Solar Cells with High Open-Circuit Voltage
文献类型：期刊论文
| 作者 | Liu, Qian1,2; Zhan, Hongmei1,2; Ho, Cheuk-Lam1,2; Dai, Feng-Rong1,2; Fu, Yingying3; Xie, Zhiyuan3; Wang, Lixiang3; Li, Jin-Hua4; Yan, Feng4; Huang, Shu-Ping5,6 |
| 刊名 | CHEMISTRY-AN ASIAN JOURNAL
 |
| 出版日期 | 2013-08-01 |
| 卷号 | 8期号:8页码:1892-1900 |
| 关键词 | Arylene Ethynylenes Donor-acceptor Systems Molecular Electronics Organic Solar Cells |
| ISSN号 | 1861-4728 |
| DOI | 10.1002/asia.201300244 |
| 英文摘要 | A new series of conjugated oligothiophene-bridged bis(arylene ethynylene) small molecules have been designed, synthesized, and characterized by photophysical, electrochemical and computational methods. These compounds were found to have optimal LUMO levels that ensure effective charge transfer from these compounds to [6,6]-phenyl-C71-butyric acid methyl ester (PC70BM). They were utilized as good electron-donor materials that can be blended with electron-acceptor PC70BM in the fabrication of solution-processed molecular bulk heterojunction (BHJ) solar cells. All of these BHJ devices showed very high open-circuit voltage (Voc) of 0.90-0.97V, and the best power conversion efficiency achieved was 3.68%. The high Voc is consistent with the deeper low-lying HOMO level and is relatively insensitive to the donor:acceptor blend ratio. The spin-coated thin films of these small molecules showed p-channel field-effect charge transport with the hole mobilities of up to 2.04x10-4cm2V-1s-1. These compounds illuminate the potential of solution-processible small-molecular aryl acetylide compounds for efficient power generation in photovoltaic implementation. |
| 语种 | 英语 |
| WOS记录号 | WOS:000325926700034 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54751]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ho, Cheuk-Lam |
| 作者单位 | 1.Hong Kong Baptist Univ, Dept Chem, Inst Mol Funct Mat, Kowloon Tong, Hong Kong, Peoples R China 2.Hong Kong Baptist Univ, Inst Adv Mat, Kowloon Tong, Hong Kong, Peoples R China 3.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Changchun Inst Appl Chem, Changchun 130022, Peoples R China 4.Hong Kong Polytech Univ, Dept Appl Phys, Hong Kong, Hong Kong, Peoples R China 5.Kyushu Univ, Inst Mat Chem & Engn, Fukuoka 8190395, Japan 6.Kyushu Univ, Int Res Ctr Mol Syst, Fukuoka 8190395, Japan |
| 推荐引用方式 GB/T 7714 | Liu, Qian,Zhan, Hongmei,Ho, Cheuk-Lam,et al. Oligothiophene-Bridged Bis(arylene ethynylene) Small Molecules for Solution-Processible Organic Solar Cells with High Open-Circuit Voltage[J]. CHEMISTRY-AN ASIAN JOURNAL,2013,8(8):1892-1900. |
| APA | Liu, Qian.,Zhan, Hongmei.,Ho, Cheuk-Lam.,Dai, Feng-Rong.,Fu, Yingying.,...&Wong, Wai-Yeung.(2013).Oligothiophene-Bridged Bis(arylene ethynylene) Small Molecules for Solution-Processible Organic Solar Cells with High Open-Circuit Voltage.CHEMISTRY-AN ASIAN JOURNAL,8(8),1892-1900. |
| MLA | Liu, Qian,et al."Oligothiophene-Bridged Bis(arylene ethynylene) Small Molecules for Solution-Processible Organic Solar Cells with High Open-Circuit Voltage".CHEMISTRY-AN ASIAN JOURNAL 8.8(2013):1892-1900. |
入库方式： OAI收割
来源：化学研究所
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