Novel Polyethylenes via Late Transition Metal Complex Pre-catalysts
文献类型：期刊论文
| 作者 | Sun, Wen-Hua ; Kaminsky, W
|
| 刊名 | POLYOLEFINS: 50 YEARS AFTER ZIEGLER AND NATTA II: POLYOLEFINS BY METALLOCENES AND OTHER SINGLE-SITE CATALYSTS
 |
| 出版日期 | 2013 |
| 卷号 | 258页码:163-178 |
| 关键词 | Branched Polyethylene Ethylene Oligomerization Late-transition Metal Linear Polyethylene Polymerization |
| ISSN号 | 0065-3195 |
| DOI | 10.1007/12_2013_212 |
| 英文摘要 | Late-transition metal complex pre-catalysts provide alternative promising catalytic systems for ethylene oligomerization and/or polymerization. Ethylene oligomerization using either iron or cobalt complex pre-catalysts is recognized as one of most active catalytic systems with high selectivity for a-olefins (up to 99%). New characteristic features are observed for the polyethylenes obtained from such late-transition metal catalytic systems. Highly linear polyethylene is usually obtained using the iron or cobalt complex pre-catalysts, whereas highly branched polyethylene is commonly formed by the nickel or palladium complex pre-catalysts. The causes for production of linear or branched polyethylenes are briefly explained according to the polymerization mechanism. Driven by demanding for new promising catalytic processes, the discussion is divided on the basis of models of complex pre-catalysts: a section on iron and cobalt complexes and another section on nickel and palladium complexes. The iron and nickel complex pre-catalysts receive more attention due to the relatively cheap and low toxicity metals from which they are derived. |
| 语种 | 英语 |
| WOS记录号 | WOS:000335560000007 |
| 出版者 | SPRINGER-VERLAG BERLIN |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54843]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Wen-Hua,Kaminsky, W. Novel Polyethylenes via Late Transition Metal Complex Pre-catalysts[J]. POLYOLEFINS: 50 YEARS AFTER ZIEGLER AND NATTA II: POLYOLEFINS BY METALLOCENES AND OTHER SINGLE-SITE CATALYSTS,2013,258:163-178. |
| APA | Sun, Wen-Hua,&Kaminsky, W.(2013).Novel Polyethylenes via Late Transition Metal Complex Pre-catalysts.POLYOLEFINS: 50 YEARS AFTER ZIEGLER AND NATTA II: POLYOLEFINS BY METALLOCENES AND OTHER SINGLE-SITE CATALYSTS,258,163-178. |
| MLA | Sun, Wen-Hua,et al."Novel Polyethylenes via Late Transition Metal Complex Pre-catalysts".POLYOLEFINS: 50 YEARS AFTER ZIEGLER AND NATTA II: POLYOLEFINS BY METALLOCENES AND OTHER SINGLE-SITE CATALYSTS 258(2013):163-178. |
入库方式： OAI收割
来源：化学研究所
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