Synthesis of Poly (3-Alkylthiophene)s
文献类型：期刊论文
| 作者 | Chen Zhouqun1,2,3; Ma Chang-Qi1 |
| 刊名 | PROGRESS IN CHEMISTRY
 |
| 出版日期 | 2013-07-24 |
| 卷号 | 25期号:7页码:1166-1176 |
| 关键词 | Conjugated Polymer Poly (3-alkylthiophene) Structural Regularity Metal-catalyzed C-c Coupling C-h Activated Polymerization |
| ISSN号 | 1005-281X |
| 英文摘要 | Owing to their excellent optoelectronic properties, poly (3-alkylthiophene)s (P3AT) has been considered as one of the best conjugated polymers for use in organic electronics devices, such as, organic field-effect transistors (OFET), organic light-emitting diodes (OLED), and organic photovoltaics (OPV). Because of the asymmetrical structure of 3-alkylthiophene, there are three possible linkages between two neighboring thiophene units, which leads to the regioregularity issues for P3AT. In comparison with regiorandom P3AT, the regioregular P3ATs exhibit better optoelectronic performance, and have attracted much attention. Synthesis of the regioregular P3AT is, however, more challenging for synthetic polymer scientists. Over the past three decades, various metal-catalyzed C-C coupling reaction have been utilized for synthesis of regioregular P3AT, including McCullough method, Rieke method, Grignard methathesis (GRIM), Suzuki-coupling, Stille-coupling, and C-H activated polymerization. In this mini-review paper, the above mentioned synthetic methods are summarized. The mechanism and advantages of these methods are compared and discussed. The current review paper gives an general overview on the research development on the synthesis of P3AT. In the end, we would like point out that direct C-H activated polymerization is the most promising synthetic method for conjugated polymers due to its high atom economy efficiency. |
| 语种 | 英语 |
| WOS记录号 | WOS:000322056300012 |
| 出版者 | CHINESE ACAD SCIENCES |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/54951]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ma Chang-Qi |
| 作者单位 | 1.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Printable Elect Res Ctr, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen Zhouqun,Ma Chang-Qi. Synthesis of Poly (3-Alkylthiophene)s[J]. PROGRESS IN CHEMISTRY,2013,25(7):1166-1176. |
| APA | Chen Zhouqun,&Ma Chang-Qi.(2013).Synthesis of Poly (3-Alkylthiophene)s.PROGRESS IN CHEMISTRY,25(7),1166-1176. |
| MLA | Chen Zhouqun,et al."Synthesis of Poly (3-Alkylthiophene)s".PROGRESS IN CHEMISTRY 25.7(2013):1166-1176. |
入库方式： OAI收割
来源：化学研究所
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