Synthesis of soluble poly(3-hexyl-2,5-thienylene vinylene) from thiophene
文献类型：期刊论文
| 作者 | Zhou, GJ; Ye, C |
| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 2004-12-01 |
| 卷号 | 22期号:6页码:549-557 |
| 关键词 | Solubility Conjugated Polymer Poly(3-hexyl-2 5-thienylene Vinylene) |
| ISSN号 | 0256-7679 |
| 英文摘要 | Soluble poly(3-hexyl-2,5-thienylene vinylene) (PHTV) was readily synthesized from thiophene in a yield better than that of the precursor method to prepare poly(thienylene vinylene) (PTV). The bandgap of the polymer is about 1.8 eV, which is comparable with that of PTV. Owing to the introduction of alkyl side groups onto the backbone of the polymer, it can be dissolved in common organic solvents such as chloroform, THF and toluene. The synthesis of soluble PHTV is a very important approach to preventing oxidation and to improving the properties and the processbility of the PTV. The existence of alkyl side groups in PHTV does not affect its, bandgap and thermal properties as compared with PTV. After doping with FeCl3, the conductivity of PHTV is as high as 1.1 x 10(-2) S/cm. The soluble PHTV can be easily transformed into thin film with much better quality than that of the PTV film prepared by the traditional precursor method, which is very important for fabricating devices with good properties. |
| 语种 | 英语 |
| WOS记录号 | WOS:000225897700008 |
| 出版者 | SPRINGER HEIDELBERG |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55053]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ye, C |
| 作者单位 | Chinese Acad Sci, Ctr Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, GJ,Ye, C. Synthesis of soluble poly(3-hexyl-2,5-thienylene vinylene) from thiophene[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2004,22(6):549-557. |
| APA | Zhou, GJ,&Ye, C.(2004).Synthesis of soluble poly(3-hexyl-2,5-thienylene vinylene) from thiophene.CHINESE JOURNAL OF POLYMER SCIENCE,22(6),549-557. |
| MLA | Zhou, GJ,et al."Synthesis of soluble poly(3-hexyl-2,5-thienylene vinylene) from thiophene".CHINESE JOURNAL OF POLYMER SCIENCE 22.6(2004):549-557. |
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来源：化学研究所
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