Self-assembly of bis(pyrrol-2-ylmethyleneamine) ligands with Cu-II controlled by bridging [-(CH2)(n)-] spacers and weak intermolecular C-H center dot center dot center dot Cu hydrogen bonding
文献类型：期刊论文
| 作者 | Yang, LY; Chen, QQ; Li, Y; Xiong, SX; Li, GP; Ma, JS |
| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2004-04-02 |
| 期号 | 7页码:1478-1487 |
| 关键词 | Copper Helical Structures Hydrogen Bonding n Ligands Schiff Bases Self-assembly |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.200300639 |
| 英文摘要 | Bis(pyrrol-2-ylmetyhleneamine) ligands linked by alkyl spacers between the imine nitrogens are shown to give di-nuclear dimers or mononuclear monomers, depending on the length of the alkyl linker, upon coordination with Cu-II. Ligands containing ethylene or hexylene linkers -(CH2)(n)- (n = 2, 6) give dinuclear dimers 5 and 8, while propylene and butylene chains (n = 3, 4) give mononuclear monomers 6 and 7. X-ray crystal structural analysis reveals that 5 exists as two very similar isomers 5a and 5b, in which the two ligands are bound to two Cu-II centers to form a distorted helical conformation. In the unit cells of 8, two entirely different isomers 8a and 8b are found. In 8a two ligands are side-by-side bound to two Cu-II centers to form a rectangular macrocycle, while in 8b they are bonded to two Cu-II centers to form a distorted double-stranded helix. Moreover, X-ray structural analysis reveals that complexes 5-8 are further assembled into one-dimensional polymers through weak, intermolecular C-H... Cu hydrogen bonding, which plays a crucial role in stabilizing the crystal lattice. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004). |
| 语种 | 英语 |
| WOS记录号 | WOS:000220797100015 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55157]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ma, JS |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.BioMarin Pharmaceut Inc, Novato, CA 94949 USA 3.Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, LY,Chen, QQ,Li, Y,et al. Self-assembly of bis(pyrrol-2-ylmethyleneamine) ligands with Cu-II controlled by bridging [-(CH2)(n)-] spacers and weak intermolecular C-H center dot center dot center dot Cu hydrogen bonding[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2004(7):1478-1487. |
| APA | Yang, LY,Chen, QQ,Li, Y,Xiong, SX,Li, GP,&Ma, JS.(2004).Self-assembly of bis(pyrrol-2-ylmethyleneamine) ligands with Cu-II controlled by bridging [-(CH2)(n)-] spacers and weak intermolecular C-H center dot center dot center dot Cu hydrogen bonding.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(7),1478-1487. |
| MLA | Yang, LY,et al."Self-assembly of bis(pyrrol-2-ylmethyleneamine) ligands with Cu-II controlled by bridging [-(CH2)(n)-] spacers and weak intermolecular C-H center dot center dot center dot Cu hydrogen bonding".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .7(2004):1478-1487. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。