Synthesis and characterization of a novel reactive ladder-like polysilsesquioxane with lateral bromophenyl groups
文献类型：期刊论文
| 作者 | Li, H; Yu, SY; Shen, ZR; Zhang, ZX; Duan, QH; Jiang, JQ; Xie, P; Zhang, RB |
| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 2004-09-01 |
| 卷号 | 22期号:5页码:445-451 |
| 关键词 | Ladder-like Polysilsesquioxane Stepwise Coupling Polymerization Hydrosilylation |
| ISSN号 | 0256-7679 |
| 英文摘要 | A novel soluble, reactive ladder-like polysilsesquioxane (L) with lateral bromophenyl groups was synthesized successfully by stepwise coupling polymerization (SCP) method including preaminolysis, hydrolysis and polycondensation steps. The monomer 3-trichlorosilylpropoxy-4-bromobenzene (M) was first prepared via hydrosilylation reaction catalyzed by dicyclopentadienylplatinum (II) dichloride (Cp2PtCl2). The title polymer (L) was characterized by H-1-NMR, Si-29-NMR, FTIR, X-ray diffraction (XRD), DSC and vapor pressure osmometry (VPO). The experimental results indicate that the polymer (L) possesses a typical ladder-like structure. |
| 语种 | 英语 |
| WOS记录号 | WOS:000224529000006 |
| 出版者 | SPRINGER HEIDELBERG |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55169]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, RB |
| 作者单位 | Chinese Acad Sci, Inst Chem, PCLCC, State Key Lab Polymer Phys & Chem,Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, H,Yu, SY,Shen, ZR,et al. Synthesis and characterization of a novel reactive ladder-like polysilsesquioxane with lateral bromophenyl groups[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2004,22(5):445-451. |
| APA | Li, H.,Yu, SY.,Shen, ZR.,Zhang, ZX.,Duan, QH.,...&Zhang, RB.(2004).Synthesis and characterization of a novel reactive ladder-like polysilsesquioxane with lateral bromophenyl groups.CHINESE JOURNAL OF POLYMER SCIENCE,22(5),445-451. |
| MLA | Li, H,et al."Synthesis and characterization of a novel reactive ladder-like polysilsesquioxane with lateral bromophenyl groups".CHINESE JOURNAL OF POLYMER SCIENCE 22.5(2004):445-451. |
入库方式： OAI收割
来源：化学研究所
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