Asymmetric hydration of alkenes catalyzed by wool-palladium complex
文献类型：期刊论文
| 作者 | Xue, L; Jia, B; Tang, L; Ji, XF; Huang, MY; Jiang, YY |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2004-06-01 |
| 卷号 | 15期号:6页码:346-349 |
| 关键词 | Wool-pd Complex Asymmetric Hydration 1-octene 1-decene (r)-(+)-2-octanol (s)-(+)-2-decanol |
| ISSN号 | 1042-7147 |
| DOI | 10.1002/pat.440 |
| 英文摘要 | A wool-palladium complex has been found to be able to catalyze the asymmetric hydration of 1-octene to (S)-(+)-2-octanol and 1-decene to (R)-(+)-2-decanol under 1 atm N-2 and at 70degreesC. The optical yields were greatly affected by Pd content in wool-palladium complex, reaction time and so on, when the proper conditions were selected, (S)-(+)-2-octanol and (R)-(+)-2-decanol could be obtained in 83.2 and 75.6%e.e. optical yield respectively. This chiral natural biopolymer-palladium complex catalyst was very easy to prepare and could be reused several times without appreciable change in catalytic activity. Copyright (C) 2004 John Wiley Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000221802200010 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55215]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jia, B |
| 作者单位 | Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, L,Jia, B,Tang, L,et al. Asymmetric hydration of alkenes catalyzed by wool-palladium complex[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2004,15(6):346-349. |
| APA | Xue, L,Jia, B,Tang, L,Ji, XF,Huang, MY,&Jiang, YY.(2004).Asymmetric hydration of alkenes catalyzed by wool-palladium complex.POLYMERS FOR ADVANCED TECHNOLOGIES,15(6),346-349. |
| MLA | Xue, L,et al."Asymmetric hydration of alkenes catalyzed by wool-palladium complex".POLYMERS FOR ADVANCED TECHNOLOGIES 15.6(2004):346-349. |
入库方式： OAI收割
来源：化学研究所
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