Electrochemical reduction of supercritical carbon dioxide in ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate
文献类型：期刊论文
| 作者 | Zhao, GY; Jiang, T; Han, BX; Li, ZH; Zhang, JM; Liu, ZM; He, J; Wu, WZ |
| 刊名 | JOURNAL OF SUPERCRITICAL FLUIDS
 |
| 出版日期 | 2004-12-01 |
| 卷号 | 32期号:1-3页码:287-291 |
| 关键词 | Supercritical Co2 Electrolysis Lonic Liquid Water Extraction |
| ISSN号 | 0896-8446 |
| DOI | 10.1016/j.supflu.2003.12.015 |
| 英文摘要 | Using 1-n-butyl-3-methylimidazolium hexafluorophosphate, (BmimPF(6)) as a solvent and electrolyte, supercritical (SC) CO2 and water were successfully electrolyzed, and the products were CO, H-2, and small amount of formic acid. The Faradic efficiency (FE) of CO increases considerably as the pressure is increased. In contrast, the FE for H-2 decreases as the pressure Of CO2 rises. After the electrolysis, the products were extracted with SC CO2 and the BmimPF(6) could be reused. This offers a new and clean route to use SC Co-2. (C) 2004 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000225199000030 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55217]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, BX |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, GY,Jiang, T,Han, BX,et al. Electrochemical reduction of supercritical carbon dioxide in ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate[J]. JOURNAL OF SUPERCRITICAL FLUIDS,2004,32(1-3):287-291. |
| APA | Zhao, GY.,Jiang, T.,Han, BX.,Li, ZH.,Zhang, JM.,...&Wu, WZ.(2004).Electrochemical reduction of supercritical carbon dioxide in ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate.JOURNAL OF SUPERCRITICAL FLUIDS,32(1-3),287-291. |
| MLA | Zhao, GY,et al."Electrochemical reduction of supercritical carbon dioxide in ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate".JOURNAL OF SUPERCRITICAL FLUIDS 32.1-3(2004):287-291. |
入库方式： OAI收割
来源：化学研究所
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