Morphological structure of solution-cast poly (trimethylene terephthalate) thin film
文献类型:期刊论文
作者 | He, XQ; Yang, DC; Xie, DM |
刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
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出版日期 | 2004-12-10 |
卷号 | 25期号:12页码:2379-2380 |
关键词 | Poly(Trimethylene Terephthalate) Morphological Structure Ring-banded Spherulite |
ISSN号 | 0251-0790 |
英文摘要 | The morphological structure of poly (trimethylene terephthalate) (PTT) thin films solution-cast at various temperatures was investigated by using polarized light microscopy and atomic force microscopy techniques. Different morphologies of the PTT films were observed at different crystallization temperatures (T-c). In the temperature range of 363-403 K, banded spherulites occurred. When T-c=413 K, the center location of the spherulite showed banded structure, while the outer region of the spherulite displayed a spherulite structure without ring-band. When T(c)greater than or equal to423 K, the normal non-banded spherulite was found. The main reason for producing the ring-banded spherulite is the effect of residual solvent during the crystallization processs of the solution-cast films. At higher crystallization temperatures (greater than or equal to423 K), no residual solvent exists during the crystallization of the films since the evaporation rate is higher at higher temperatures. So no banded structure is formed. |
语种 | 英语 |
WOS记录号 | WOS:000225904200046 |
出版者 | HIGHER EDUCATION PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/55265] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Yang, DC |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China |
推荐引用方式 GB/T 7714 | He, XQ,Yang, DC,Xie, DM. Morphological structure of solution-cast poly (trimethylene terephthalate) thin film[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,25(12):2379-2380. |
APA | He, XQ,Yang, DC,&Xie, DM.(2004).Morphological structure of solution-cast poly (trimethylene terephthalate) thin film.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,25(12),2379-2380. |
MLA | He, XQ,et al."Morphological structure of solution-cast poly (trimethylene terephthalate) thin film".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 25.12(2004):2379-2380. |
入库方式: OAI收割
来源:化学研究所
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