中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and properties of poly (4,4 '-oxybis (benzene)disulfide)/graphite nanocomposites via in situ ring-opening polymerization of macrocyclic oligomers

文献类型:期刊论文

作者Du, XS; Xiao, M; Meng, YZ; Hay, AS
刊名POLYMER
出版日期2004-09-03
卷号45期号:19页码:6713-6718
关键词Conducting Polymer Macrocyclics Graphite
ISSN号0032-3861
DOI10.1016/j.polymer.2004.07.026
英文摘要An effective method for the preparation of poly(4,4'-oxybis(benzene)disulfide)/graphite nanosheet composites via in situ ring-opening polymerization of macrocyclic oligomers were reported. Completely exfoliated graphite nanosheets were prepared under the microwave irradiation followed by sonication in solution. The nanocomposites were fabricated via in situ melt ring-opening polymerization of macrocyclic oligomers in the presence of graphite nanosheets. The graphite nanosheets and resulted poly(arylene disulfide)/graphite nanocomposites were characterized with field emission scanning electron microscope (FE-SEM), transmission electron microscope (TEM), tensile tester and electrical conductivity measurements. Compared with pure polymer, the electrical conductivity of the poly(arylene disulfide)/graphite nanocomposites were dramatically increased and had a value of about 10(-3) S/cm for the nanocomposite containing 5 wt% graphite. The nanocomposites exhibit as both high performance polymeric material and electrically conductive material. Therefore, they show potential applications as high temperature conducting materials. (C) 2004 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000223694200035
出版者ELSEVIER SCI LTD
源URL[http://ir.iccas.ac.cn/handle/121111/55325]  
专题中国科学院化学研究所
通讯作者Meng, YZ
作者单位1.Sun Yat Sen Univ, Inst Energy & Environm Mat, Sch Phys & Engn, Guangzhou 510275, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
3.McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
推荐引用方式
GB/T 7714
Du, XS,Xiao, M,Meng, YZ,et al. Synthesis and properties of poly (4,4 '-oxybis (benzene)disulfide)/graphite nanocomposites via in situ ring-opening polymerization of macrocyclic oligomers[J]. POLYMER,2004,45(19):6713-6718.
APA Du, XS,Xiao, M,Meng, YZ,&Hay, AS.(2004).Synthesis and properties of poly (4,4 '-oxybis (benzene)disulfide)/graphite nanocomposites via in situ ring-opening polymerization of macrocyclic oligomers.POLYMER,45(19),6713-6718.
MLA Du, XS,et al."Synthesis and properties of poly (4,4 '-oxybis (benzene)disulfide)/graphite nanocomposites via in situ ring-opening polymerization of macrocyclic oligomers".POLYMER 45.19(2004):6713-6718.

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来源:化学研究所

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