Hydrodynamic radius characterization of a vinyl-type polynorbornene by size-exclusion chromatography with a static and dynamic laser light scattering detector
文献类型:期刊论文
作者 | Liu, Y; Bo, S |
刊名 | CHROMATOGRAPHIA
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出版日期 | 2004-03-01 |
卷号 | 59期号:5-6页码:299-303 |
关键词 | Column Liquid Chromatography Size-exclusion Chromatography Laser Light Scattering Detection Polynorbornene |
ISSN号 | 0009-5893 |
DOI | 10.1365/s10337-003-0160-1 |
英文摘要 | Both absolute molecular weight and molecular sizes (radius of gyration and hydrodynamic radius) of a vinyl-type polynorbornene eluting from size-exclusion chromatography columns were determined by combined with a static and dynamic laser light scattering detector. The hydrodynamic radius of polymer fraction eluting from size-exclusion chromatography columns was obtained from dynamic laser light scattering measurements at only a single angle of 900 by introducing a correction factor. According to the scaling relationship between molecular sizes and molecular weight and the ratio between radius of gyration and hydrodynamic radius, the vinyl-type polynorbornene took a random coil conformation in 1,2,4-trichlorobenzene at 150 degreesC. |
语种 | 英语 |
WOS记录号 | WOS:000224099900005 |
出版者 | VIEWEG |
源URL | [http://ir.iccas.ac.cn/handle/121111/55435] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Bo, S |
作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, Y,Bo, S. Hydrodynamic radius characterization of a vinyl-type polynorbornene by size-exclusion chromatography with a static and dynamic laser light scattering detector[J]. CHROMATOGRAPHIA,2004,59(5-6):299-303. |
APA | Liu, Y,&Bo, S.(2004).Hydrodynamic radius characterization of a vinyl-type polynorbornene by size-exclusion chromatography with a static and dynamic laser light scattering detector.CHROMATOGRAPHIA,59(5-6),299-303. |
MLA | Liu, Y,et al."Hydrodynamic radius characterization of a vinyl-type polynorbornene by size-exclusion chromatography with a static and dynamic laser light scattering detector".CHROMATOGRAPHIA 59.5-6(2004):299-303. |
入库方式: OAI收割
来源:化学研究所
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