Synthesis and characterization of new polybenzimidazopyrrolones derived from pyridine-bridged aromatic tetraamines and dianhydrides
文献类型:期刊论文
作者 | Liu, JG; Wang, LF; Yang, HX; Li, HS; Li, YF; Fan, L; Yang, SY |
刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
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出版日期 | 2004-04-15 |
卷号 | 42期号:8页码:1845-1856 |
关键词 | Tetraamine Polypyrrolone Pyridine High Performance Polymers Films Thermal Properties Hydrolysis Resistance |
ISSN号 | 0887-624X |
DOI | 10.1002/pola.20030 |
英文摘要 | A series of new polybenzimidazopyrrolones (polypyrrolone, PPy) were synthesized by polycondensation of pyridine-bridged aromatic tetraamines, including 2,6-bis (3',4'-diaminophenyl)-4-phenylpyridine and 2,6-bis(3',4'- diaminophenyl)-4-(3"-trifluoromethyl)phenyl pyridine, with various aromatic dianhydrides. Experimental results indicated that the PPys, multiaromatic conjugated and semiladder polymers, showed good thermal stabilities with thermal-decomposition temperatures of about 500degreesC and residual weight retention at 750degreesC as high as 84%. PPy films could be obtained by casting the precursor solution, poly(amide amino acid) on glass substrate, followed by thermal dehydrating at elevated temperatures. The polymer films exhibited excellent alkaline hydrolysis resistance, which retained their original shapes and toughness after boiling 7 days in 10% sodium hydroxide solution. (C) 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1845-1856, 2004. |
语种 | 英语 |
WOS记录号 | WOS:000220547500005 |
出版者 | JOHN WILEY & SONS INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/55437] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Yang, SY |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Adv Polymer Mat, Beijing 100080, Peoples R China 2.Lanzhou Univ, Sch Chem & Chem Engn, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, JG,Wang, LF,Yang, HX,et al. Synthesis and characterization of new polybenzimidazopyrrolones derived from pyridine-bridged aromatic tetraamines and dianhydrides[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2004,42(8):1845-1856. |
APA | Liu, JG.,Wang, LF.,Yang, HX.,Li, HS.,Li, YF.,...&Yang, SY.(2004).Synthesis and characterization of new polybenzimidazopyrrolones derived from pyridine-bridged aromatic tetraamines and dianhydrides.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,42(8),1845-1856. |
MLA | Liu, JG,et al."Synthesis and characterization of new polybenzimidazopyrrolones derived from pyridine-bridged aromatic tetraamines and dianhydrides".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 42.8(2004):1845-1856. |
入库方式: OAI收割
来源:化学研究所
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