Crystal growth, structure and conductivity of the BEDT-TTF-based charge-transfer salt (BEDT-TTF)(2)C3H5SO3 center dot H2O
文献类型：期刊论文
| 作者 | Liu, Z; Yu, WT; Jiang, MH; Zhang, DQ; Zhu, DB |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2004-04-14 |
| 卷号 | 62期号:7页码:686-691 |
| 关键词 | Bedt-ttf Electrocrystallization Crystal Structure Semiconductor |
| ISSN号 | 0567-7351 |
| 英文摘要 | A new BEDT-TIT-based charge-transfer salt, ( BEDT-TTF)(2)C3H5SO3 (.) H2O ( BEDT-TIT = bis(ethylenedithio) tetrathiafulvalene, C3H5SO3- = allylsulfonate), has been prepared by oxidative electro-crystallization at a constant current of 1.5 muA. The single crystal structure was determined by four-circle X-ray diffraction method. The crystal belongs to orthorhombic system, Pma2 space group with the unit cell parameters of a=3.2772(3) rim, b = 0.79604(7) um, c = 0.66868(7) nm, V = 1.7445(3) nm(3). In the crystal of the title compound, the BEDT-TTF cations adopt an alpha'-type packing pattern and organic counter anions form infinite chains by hydrogen bonds along c,axis. The room-temperature conductivity of the salt is 0.0489 Omega(-1) (.) m(-1). The resistivity-temperature curve demonstrates that it is a typical semiconductor with an activation of 0.319 eV. |
| 语种 | 英语 |
| WOS记录号 | WOS:000220682300008 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55449]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Z |
| 作者单位 | 1.Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Z,Yu, WT,Jiang, MH,et al. Crystal growth, structure and conductivity of the BEDT-TTF-based charge-transfer salt (BEDT-TTF)(2)C3H5SO3 center dot H2O[J]. ACTA CHIMICA SINICA,2004,62(7):686-691. |
| APA | Liu, Z,Yu, WT,Jiang, MH,Zhang, DQ,&Zhu, DB.(2004).Crystal growth, structure and conductivity of the BEDT-TTF-based charge-transfer salt (BEDT-TTF)(2)C3H5SO3 center dot H2O.ACTA CHIMICA SINICA,62(7),686-691. |
| MLA | Liu, Z,et al."Crystal growth, structure and conductivity of the BEDT-TTF-based charge-transfer salt (BEDT-TTF)(2)C3H5SO3 center dot H2O".ACTA CHIMICA SINICA 62.7(2004):686-691. |
入库方式： OAI收割
来源：化学研究所
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