中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and characterization of highly conducting PyH[Pd(dmit)(2)](2) crystal

文献类型:期刊论文

作者Fang, Q; Xu, W; Lei, H; Xu, CY; Zhang, B; Zhu, DB
刊名INORGANIC CHEMISTRY COMMUNICATIONS
出版日期2004-10-01
卷号7期号:10页码:1157-1160
关键词Palladium Complex Synthesis X-ray Crystal Structure Conductivity
ISSN号1387-7003
DOI10.1016/j.inoche.2004.08.020
英文摘要A new molecular conductor PyH[Pd(dmit)(2)](2) (PYH = pyridinium, dmit = 2-thioxo-1,3-dithiole-4,5-dithiolato) has been synthesized and structurally investigated. The room temperature conductivity at a certain direction on (0 0 1) plane was measured to be as high as a 2 x 10(2) Omega(-1) cm(-1). In the temperature range of 290-50 K, the crystal shows semi-conductivity with a small activation energy of 0.102 eV. In the range of 49-27 K, it exhibits metallic conducting behavior. (C) 2004 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000224452700020
出版者ELSEVIER SCIENCE BV
源URL[http://ir.iccas.ac.cn/handle/121111/55487]  
专题中国科学院化学研究所
通讯作者Fang, Q
作者单位1.Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
2.Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
3.Shandong Univ, Sch Informat Sci & Engn, Jinan 250100, Peoples R China
4.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Fang, Q,Xu, W,Lei, H,et al. Synthesis and characterization of highly conducting PyH[Pd(dmit)(2)](2) crystal[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2004,7(10):1157-1160.
APA Fang, Q,Xu, W,Lei, H,Xu, CY,Zhang, B,&Zhu, DB.(2004).Synthesis and characterization of highly conducting PyH[Pd(dmit)(2)](2) crystal.INORGANIC CHEMISTRY COMMUNICATIONS,7(10),1157-1160.
MLA Fang, Q,et al."Synthesis and characterization of highly conducting PyH[Pd(dmit)(2)](2) crystal".INORGANIC CHEMISTRY COMMUNICATIONS 7.10(2004):1157-1160.

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来源:化学研究所

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