Synthesis and characterization of highly conducting PyH[Pd(dmit)(2)](2) crystal
文献类型:期刊论文
作者 | Fang, Q; Xu, W; Lei, H; Xu, CY; Zhang, B; Zhu, DB |
刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
![]() |
出版日期 | 2004-10-01 |
卷号 | 7期号:10页码:1157-1160 |
关键词 | Palladium Complex Synthesis X-ray Crystal Structure Conductivity |
ISSN号 | 1387-7003 |
DOI | 10.1016/j.inoche.2004.08.020 |
英文摘要 | A new molecular conductor PyH[Pd(dmit)(2)](2) (PYH = pyridinium, dmit = 2-thioxo-1,3-dithiole-4,5-dithiolato) has been synthesized and structurally investigated. The room temperature conductivity at a certain direction on (0 0 1) plane was measured to be as high as a 2 x 10(2) Omega(-1) cm(-1). In the temperature range of 290-50 K, the crystal shows semi-conductivity with a small activation energy of 0.102 eV. In the range of 49-27 K, it exhibits metallic conducting behavior. (C) 2004 Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000224452700020 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iccas.ac.cn/handle/121111/55487] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Fang, Q |
作者单位 | 1.Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China 3.Shandong Univ, Sch Informat Sci & Engn, Jinan 250100, Peoples R China 4.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Fang, Q,Xu, W,Lei, H,et al. Synthesis and characterization of highly conducting PyH[Pd(dmit)(2)](2) crystal[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2004,7(10):1157-1160. |
APA | Fang, Q,Xu, W,Lei, H,Xu, CY,Zhang, B,&Zhu, DB.(2004).Synthesis and characterization of highly conducting PyH[Pd(dmit)(2)](2) crystal.INORGANIC CHEMISTRY COMMUNICATIONS,7(10),1157-1160. |
MLA | Fang, Q,et al."Synthesis and characterization of highly conducting PyH[Pd(dmit)(2)](2) crystal".INORGANIC CHEMISTRY COMMUNICATIONS 7.10(2004):1157-1160. |
入库方式: OAI收割
来源:化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。