Oxidative degradation of organic pollutants utilizing molecular oxygen and visible light over a supported catalyst of Fe(bpy)(3)(2+) in water
文献类型：期刊论文
| 作者 | Li, J; Ma, WH; Huang, YP; Tao, X; Zhao, JC; Xu, YM |
| 刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
 |
| 出版日期 | 2004-03-08 |
| 卷号 | 48期号:1页码:17-24 |
| 关键词 | Dioxygen Activation Iron Complex Photodegradation Pollutant |
| ISSN号 | 0926-3373 |
| DOI | 10.1016/j.apcatb.2003.09.003 |
| 英文摘要 | This article explores a supported catalyst of Fe(bpy)(3)(2+) on a cationic exchange resin (Amberlite IRA 200) as a photocatalyst for the degradation of organic pollutants by activating molecular oxygen under visible irradiation (lambda > 420 nm) in water. Different from Fe(bpy)(3)(2+) which is not photoactive in solution, the supported catalyst exhibits a very efficient photoactivity for the degradation of N,N-dimethylaniline and the cationic dyes of Rhodamine B (RhB) and Malachite Green (MG) in an aerated aqueous medium. TOC removal yield was 75, 60 and 58%, respectively, after 700 min of visible light irradiation. The photocatalytic activity of the supported Fe(bpy)(3)(2+) remained unchanged after 22 cycles of over 100 h. The photocatalyst was characterized by UV-Vis diffuse reflectance, and X-ray photoelectron spectroscopies (XPS). EPR studies suggest that the active superoxide species {Fe(bpy)(3)(3+) O-2(.-)} are involved in the light-activated reaction. A reaction mechanism is proposed in the text. (C) 2003 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000220269800002 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55489]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhao, JC |
| 作者单位 | 1.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Lab Photochem, Beijing 100080, Peoples R China 2.Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, J,Ma, WH,Huang, YP,et al. Oxidative degradation of organic pollutants utilizing molecular oxygen and visible light over a supported catalyst of Fe(bpy)(3)(2+) in water[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2004,48(1):17-24. |
| APA | Li, J,Ma, WH,Huang, YP,Tao, X,Zhao, JC,&Xu, YM.(2004).Oxidative degradation of organic pollutants utilizing molecular oxygen and visible light over a supported catalyst of Fe(bpy)(3)(2+) in water.APPLIED CATALYSIS B-ENVIRONMENTAL,48(1),17-24. |
| MLA | Li, J,et al."Oxidative degradation of organic pollutants utilizing molecular oxygen and visible light over a supported catalyst of Fe(bpy)(3)(2+) in water".APPLIED CATALYSIS B-ENVIRONMENTAL 48.1(2004):17-24. |
入库方式： OAI收割
来源：化学研究所
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