Studies on the characteristics of the coordinated units of methyl acrylate and vinyl pyridine copolymer rhodium complexes and their influence on catalytic properties
文献类型：期刊论文
| 作者 | Shi, XL; Yu, DS; Qian, QL; Zou, J; Pan, PL; Yuan, GQ; Shao, SY; Ling, C |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2004-04-01 |
| 期号 | 2页码:219-222 |
| 关键词 | Methanol Carbonylation Vinyl Pyridine Pmv And Pmv' Copolymer Rhodium Complexes Coordination Units |
| ISSN号 | 1000-3304 |
| 英文摘要 | By using X-ray photoelectron spectroscopy and IR spectroscopy, a series of coordination units of methyl acrylate (M) and 2-vinyl pyridine (V) copolymer rhodium complexes were studied in comparison with those of methyl acrylate (M) and 4-vinyl pyridine (V') copolymer rhodium complexes. The influence of the microstructures of their active centers and reaction temperature on their catalytic activity for methanol carbonylation was investigated by well-directed experiments. It has been found that the complexes containing methyl acrylate(M) and 2-vinyl pyridine (V) copolymer ligands exhibit much higher catalytic activity than those of methyl acrylate(M) and 4-vinyl pyridine (V') copolymer rhodium complexes on carbonylation of methanol. It is suggested that the 2-substituted vinyl pyridine possesses the favored catalytic microstructure for such reactions. These experimental observations provided theoretical and practical incentive to further investigation. |
| 语种 | 英语 |
| WOS记录号 | WOS:000220759200012 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55549]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shi, XL |
| 作者单位 | 1.Beijing Univ Chem Technol, Sch Mat Sci & Engn, Beijing 100029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 3.Jiangsu Suopo Grp Co Ltd, Zhenjiang 212006, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, XL,Yu, DS,Qian, QL,et al. Studies on the characteristics of the coordinated units of methyl acrylate and vinyl pyridine copolymer rhodium complexes and their influence on catalytic properties[J]. ACTA POLYMERICA SINICA,2004(2):219-222. |
| APA | Shi, XL.,Yu, DS.,Qian, QL.,Zou, J.,Pan, PL.,...&Ling, C.(2004).Studies on the characteristics of the coordinated units of methyl acrylate and vinyl pyridine copolymer rhodium complexes and their influence on catalytic properties.ACTA POLYMERICA SINICA(2),219-222. |
| MLA | Shi, XL,et al."Studies on the characteristics of the coordinated units of methyl acrylate and vinyl pyridine copolymer rhodium complexes and their influence on catalytic properties".ACTA POLYMERICA SINICA .2(2004):219-222. |
入库方式： OAI收割
来源：化学研究所
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