Calculation of thermodynamic properties of polymer solutions by path integral method
文献类型：期刊论文
| 作者 | Qiao, BF; Zhao, DL |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2004-04-01 |
| 期号 | 2页码:153-159 |
| 关键词 | Path Integral Method Effective Concentration Polymer Solution Phase Separation |
| ISSN号 | 1000-3304 |
| 英文摘要 | It is proposed that the overall free energy of a polymer solution has three fundamentally different types of contributions, i.e. the translational, the configurational and the thermal correction parts. The second and the third parts have the additive properties for segments and can be calculated by path integral method with the introduction of a new concept of effective concentration. Taking the volume fraction as the effective concentration, one obtains the Li-Zhao theory of polymer solutions reported previously. The results calculated by the present theory match the spinodals data of PS/cyclohexane systems with different molecular weights much better than those based on the Flory-Huggins theory. |
| 语种 | 英语 |
| WOS记录号 | WOS:000220759200001 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55591]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Qiao, BF |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qiao, BF,Zhao, DL. Calculation of thermodynamic properties of polymer solutions by path integral method[J]. ACTA POLYMERICA SINICA,2004(2):153-159. |
| APA | Qiao, BF,&Zhao, DL.(2004).Calculation of thermodynamic properties of polymer solutions by path integral method.ACTA POLYMERICA SINICA(2),153-159. |
| MLA | Qiao, BF,et al."Calculation of thermodynamic properties of polymer solutions by path integral method".ACTA POLYMERICA SINICA .2(2004):153-159. |
入库方式： OAI收割
来源：化学研究所
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