中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
One-pot method of preparing novel macrocyclic (thio arylene) oligomers

文献类型:期刊论文

作者Chen, K; Liang, ZA; Meng, YZ; Hay, AS
刊名EUROPEAN POLYMER JOURNAL
出版日期2004-02-01
卷号40期号:2页码:403-408
关键词Cyclic(Thio Arylene) Cyclic Oligomer Ring-opening Polymerization
ISSN号0014-3057
DOI10.1016/j.europolymj.2003.10.008
英文摘要A series of macrocyclic(thio arylene) oligomers were synthesized under high dilution conditions by reacting diphenyl ether, diphenyl, diphenyl disulfide or diphenyl methane with dichloro disulfide in the presence of trace amount of iron powder by a one-step method. The composition of these macrocyclic oligomers was analyzed by MALDI-TOF technology, and the experimental results showed that the cyclics were a mixture with repeating units separated by one to seven sulfur atoms. These macrocyclics can undergo ring-opening polymerization to form linear polymers under mild conditions. The glass transition temperatures of produced polymers varied with the sulfur content. (C) 2003 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000188994400024
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/55669]  
专题中国科学院化学研究所
通讯作者Meng, YZ
作者单位1.Chinese Acad Sci, Guangzhou Inst Chem, Guangzhou 510650, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
3.Sun Yat Sen Univ, Sch Phys & Engn, Inst Energy & Environm Mat, Guangzhou 510275, Peoples R China
4.McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
推荐引用方式
GB/T 7714
Chen, K,Liang, ZA,Meng, YZ,et al. One-pot method of preparing novel macrocyclic (thio arylene) oligomers[J]. EUROPEAN POLYMER JOURNAL,2004,40(2):403-408.
APA Chen, K,Liang, ZA,Meng, YZ,&Hay, AS.(2004).One-pot method of preparing novel macrocyclic (thio arylene) oligomers.EUROPEAN POLYMER JOURNAL,40(2),403-408.
MLA Chen, K,et al."One-pot method of preparing novel macrocyclic (thio arylene) oligomers".EUROPEAN POLYMER JOURNAL 40.2(2004):403-408.

入库方式: OAI收割

来源:化学研究所

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