Asymmetric hydrogenation of furfuryl alcohol catalyzed by a biopolymer-metal complex, silica-supported alginic acid-amino acid-Pt complex
文献类型：期刊论文
| 作者 | Wei, WL; Zhu, HY; Zhao, CL; Huang, MY; Jiang, YY |
| 刊名 | REACTIVE & FUNCTIONAL POLYMERS
 |
| 出版日期 | 2004 |
| 卷号 | 59期号:1页码:33-39 |
| 关键词 | Silica-supported Alginic Acid-amino Acid-pt Complex Asymmetric Hydrogenation Furfuryl Alcohol (s)-(+)-tetrahydrofurfuryl Alcohol |
| ISSN号 | 1381-5148 |
| DOI | 10.1016/j.reactfunctpolym.2003.10.004 |
| 英文摘要 | A biopolymer containing metal complex, silica-supported alginic acid-amino acid (L-alanine, L-glutamic acid, L-serine or L-lysine)-Pt complex, SiO2-AA-aa-Pt (SiO2-AA-ala-Pt, SiO2-AA-glu-Pt, SiO2-AA-ser-Pt, SiO2-AA-lys-Pt) has been prepared and found to be able to catalyze the asymmetric hydrogenation of furfuryl alcohol to give (S)(+)-tetrahydrofurfuryl alcohol at 30 degreesC and under 1 atmH(2). Among of them, SiO2-AA-glu-Pt complex catalyst is most effective for this asymmetric reaction and 84.4% product yield and 98.3% ee optical yield can be obtained, respectively. This catalyst can be reused several times without large change in the optical catalytic activity. (C) 2003 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000221113100005 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55683]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wei, WL |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei, WL,Zhu, HY,Zhao, CL,et al. Asymmetric hydrogenation of furfuryl alcohol catalyzed by a biopolymer-metal complex, silica-supported alginic acid-amino acid-Pt complex[J]. REACTIVE & FUNCTIONAL POLYMERS,2004,59(1):33-39. |
| APA | Wei, WL,Zhu, HY,Zhao, CL,Huang, MY,&Jiang, YY.(2004).Asymmetric hydrogenation of furfuryl alcohol catalyzed by a biopolymer-metal complex, silica-supported alginic acid-amino acid-Pt complex.REACTIVE & FUNCTIONAL POLYMERS,59(1),33-39. |
| MLA | Wei, WL,et al."Asymmetric hydrogenation of furfuryl alcohol catalyzed by a biopolymer-metal complex, silica-supported alginic acid-amino acid-Pt complex".REACTIVE & FUNCTIONAL POLYMERS 59.1(2004):33-39. |
入库方式： OAI收割
来源：化学研究所
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