Synthesis and photophysical properties of a novel semiconducting polymer
文献类型：期刊论文
| 作者 | Huang, HM; He, QG; Lin, HZ; Bai, FL; Sun, Z; Li, QS |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2004 |
| 卷号 | 15期号:1-2页码:84-88 |
| 关键词 | Alternating Copolymer Wittig Reaction Light-emitting Material Photophysical Properties |
| ISSN号 | 1042-7147 |
| DOI | 10.1002/pat.453 |
| 英文摘要 | An alternating copolymer containing triphenylamine (TPA) and cyano-substituted benzene moieties, TPA-CNPPV was synthesized using the Wittig reaction. The monomers and polymer were characterized by H-NMR, FT-IR and mass spectroscopy (MS). The polymer shows good solubility in common organic solvents and excellent film-forming ability. Thermogravimetric analysis (TGA) demonstrates that the polymer has a degradation temperature (T-D) of 600degreesC; differential scanning calorimetry (DSC) result indicates that the glass transition temperature (T-g) of TPA-CNPPV is 160degreesC, suggesting high thermal stability. The photophysical properties of the light-emitting material were investigated in both solution and spin-coated film. Photo-isomerization of the polymer was investigated by UV-vis and fluorescence spectra. The interaction between TPA-CNPPV and C-60 was studied by fluorescence quenching. Copyright (C) 2004 John Wiley Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000189213300016 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55723]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Bai, FL |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Organ Solids, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, HM,He, QG,Lin, HZ,et al. Synthesis and photophysical properties of a novel semiconducting polymer[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2004,15(1-2):84-88. |
| APA | Huang, HM,He, QG,Lin, HZ,Bai, FL,Sun, Z,&Li, QS.(2004).Synthesis and photophysical properties of a novel semiconducting polymer.POLYMERS FOR ADVANCED TECHNOLOGIES,15(1-2),84-88. |
| MLA | Huang, HM,et al."Synthesis and photophysical properties of a novel semiconducting polymer".POLYMERS FOR ADVANCED TECHNOLOGIES 15.1-2(2004):84-88. |
入库方式： OAI收割
来源：化学研究所
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