Two novel windmill-like tetrasupporting heteropolyoxometalates: [(MO7MOV8O40)-M-VI-V-V-O-IV(PO4)][M(phen)(2)(OH)](2)[M(phen)(2)(OEt)](2) (M = Co, Ni)
文献类型：期刊论文
| 作者 | Liu, CM; Zhang, DQ; Xu, CY; Zhu, DB |
| 刊名 | SOLID STATE SCIENCES
 |
| 出版日期 | 2004-07-01 |
| 卷号 | 6期号:7页码:689-696 |
| 关键词 | Solvothermal Syntheses Crystal Structures Polyoxometalates Cobalt Nickel Magnetic Properties |
| ISSN号 | 1293-2558 |
| DOI | 10.1016/j.solidstatesciences.2004.04.003 |
| 英文摘要 | Two interesting neutral tetrasupporting heteropolyoxometalates: [(Mo7MoV8O40)-Mo-VI-V-V-O-IV(PO4)][M(phen)(2)(OH)](2)[M(phen)(2)(OEt)](2).XH2O (phen = 1,10-phenanthroline, EtOH = ethanol, M = Co, x = 7, 1; M = Ni, x = 6, 2) were hydrothermally prepared and structurally characterized. The mixed molybdenum-vanadium polyoxoanion [(Mo7MoV8O40)-Mo-VI-V-V-O-IV(PO4)](4)(-) exist in both two complexes, which acts as a bridge to covalently link two pairs of transition metal complex fragments, generating neutral windmill-like trimetallic nanocluster polyoxometalates. Variable-temperature magnetic susceptibility measurements of complexes I and 2 reveal that anti ferromagnetic exchange interaction exists in this type of trimetallic tetrasupporting heteropolyoxometalates. (C) 2004 Elsevier SAS. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000222934000010 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55735]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, CM |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, CM,Zhang, DQ,Xu, CY,et al. Two novel windmill-like tetrasupporting heteropolyoxometalates: [(MO7MOV8O40)-M-VI-V-V-O-IV(PO4)][M(phen)(2)(OH)](2)[M(phen)(2)(OEt)](2) (M = Co, Ni)[J]. SOLID STATE SCIENCES,2004,6(7):689-696. |
| APA | Liu, CM,Zhang, DQ,Xu, CY,&Zhu, DB.(2004).Two novel windmill-like tetrasupporting heteropolyoxometalates: [(MO7MOV8O40)-M-VI-V-V-O-IV(PO4)][M(phen)(2)(OH)](2)[M(phen)(2)(OEt)](2) (M = Co, Ni).SOLID STATE SCIENCES,6(7),689-696. |
| MLA | Liu, CM,et al."Two novel windmill-like tetrasupporting heteropolyoxometalates: [(MO7MOV8O40)-M-VI-V-V-O-IV(PO4)][M(phen)(2)(OH)](2)[M(phen)(2)(OEt)](2) (M = Co, Ni)".SOLID STATE SCIENCES 6.7(2004):689-696. |
入库方式： OAI收割
来源：化学研究所
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