The asymmetric hydration of 1-octene to (S)-(+)-2-octanol with a biopolymer-metal complex, silica-supported chitosan-cobalt complex
文献类型：期刊论文
| 作者 | Xue, L; Zhou, DJ; Tang, L; Ji, XF; Huang, MY; Jiang, YY |
| 刊名 | REACTIVE & FUNCTIONAL POLYMERS
 |
| 出版日期 | 2004 |
| 卷号 | 58期号:2页码:117-121 |
| 关键词 | Asymmetric Hydration Silica Supported Chitosan-cobalt Complex 1-octene (s)-(+)-2-octanol |
| ISSN号 | 1381-5148 |
| DOI | 10.1016/j.reactfunctpolym.2003.10.003 |
| 英文摘要 | A new biopolymer-non-noble metal catalyst, silica-supported chitosan-cobalt complex (SiO2-CS-Co), has been prepared by a simple method and found to be a high stereoselective catalyst for asymmetric hydration of 1-octene to (S)-(+)-2-octanol amounted to 97.8%ee when fitting conditions were selected. This catalyst was very stable and could be reused several times without any remarkable change in catalytic activity and optical selectivity. Obviously, the present work has provided a more economical alternative way for the preparation of a chiral 2-octanol. (C) 2003 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000189287200005 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55751]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xue, L |
| 作者单位 | 1.JAIST, Grad Sch Mat Sci, Tatsunokuchi, Ishikawa 9231292, Japan 2.Chinese Acad Sci, Inst Chem, Grp 4060, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, L,Zhou, DJ,Tang, L,et al. The asymmetric hydration of 1-octene to (S)-(+)-2-octanol with a biopolymer-metal complex, silica-supported chitosan-cobalt complex[J]. REACTIVE & FUNCTIONAL POLYMERS,2004,58(2):117-121. |
| APA | Xue, L,Zhou, DJ,Tang, L,Ji, XF,Huang, MY,&Jiang, YY.(2004).The asymmetric hydration of 1-octene to (S)-(+)-2-octanol with a biopolymer-metal complex, silica-supported chitosan-cobalt complex.REACTIVE & FUNCTIONAL POLYMERS,58(2),117-121. |
| MLA | Xue, L,et al."The asymmetric hydration of 1-octene to (S)-(+)-2-octanol with a biopolymer-metal complex, silica-supported chitosan-cobalt complex".REACTIVE & FUNCTIONAL POLYMERS 58.2(2004):117-121. |
入库方式： OAI收割
来源：化学研究所
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