Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes
文献类型：期刊论文
| 作者 | Liang, H; Liu, JY; Li, XF; Li, YS |
| 刊名 | POLYHEDRON
 |
| 出版日期 | 2004-05-27 |
| 卷号 | 23期号:9页码:1619-1627 |
| 关键词 | Neutral Palladium(Ii) Complex X-ray Crystallography Catalyst Methylaluminoxane Norbornene Vinylic Polymerizaition |
| ISSN号 | 0277-5387 |
| DOI | 10.1016/j.poly.2004.03.017 |
| 英文摘要 | A series of neutral palladium(II) complexes bearing non-symmetric bidentate pyrrole-iminato or salicylaldiminato chelate ligands have been synthesized, and the structure of representative complexes (3a, 4a, and 5a) have been confirmed by X-ray crystallographic analysis. These palladium complexes have been investigated as catalysts for the polymerization of norbornene. Using modified methylaluminoxane (MMAO) as a cocatalyst, these complexes display high activities and produce vinyl-addition polynorborenes. Catalytic activity of up to 8.52 x 10(3) kg/mol(Pd) h has been observed. Wide-angle X-ray diffraction (WAXD) has been used to investigate the polymer microstructure and it has been found that they are non-crystalline. (C) 2004 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000221778800016 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55801]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, YS |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liang, H,Liu, JY,Li, XF,et al. Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes[J]. POLYHEDRON,2004,23(9):1619-1627. |
| APA | Liang, H,Liu, JY,Li, XF,&Li, YS.(2004).Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes.POLYHEDRON,23(9),1619-1627. |
| MLA | Liang, H,et al."Synthesis, structure and norbornene polymerization behavior of neutral palladium complexes".POLYHEDRON 23.9(2004):1619-1627. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。