中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Photophysical processes of a fluorene derivative containing 1,3,4-oxadiazole

文献类型:期刊论文

作者Feng, LH; Chen, ZB; Bai, FL
刊名SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
出版日期2004-11-01
卷号60期号:13页码:3029-3032
关键词Exciplex Fullerene (C-60) Carbon Nanotubes (Cnts) 2-Phenyl-5-[3 '-(Methacrylamido)Phenyl]-1 9 3 9-bis(4 '-aminophenyl)Fluorene 4-oxadiazole
ISSN号1386-1425
DOI10.1016/j.saa.2004.02.019
英文摘要The photophysical processes of 9,9-bis{4'-[2"-phenyl-5"-(3"'-(methacryl-amido)phenyl)]- 1",3",4"-oxadiazolylphenyl}fluorene (F-MAOP) formed by Heck reaction of 9,9-bis(4'-iodophenyl)fluorene (F-IP) and 2-phenyl-5-[3'-(methacrylamido)phenyl]-1,3,4-oxadiazole (OXD) have been carefully studied. The results show that the compound emits blue and blue-violet light and the emission spectra exhibit obvious solvent effect. With the increase of polarity of solvents, the fluorescence spectra change obviously and appear blue shift at room temperature. In addition, the light-emitting can be quenched by both electron donor (N,N-dimethylaniline, DMA) and electron acceptor (C-60). When N,N-dimethylaniline is gradually added into the solution of F-MAOP, the emission intensities of fluorescence are unusually increased. But when the concentration of DMA beyond a certain scope, the emission intensities of fluorescence are gradually decreased. The dimolecular exciplex between F-MAOP and C-60 are formed and the quenching effect follows the Stern-Volmer equation. Moreover, interaction between F-MAOP and carbon nanotubes (CNTs) is also studied by fluorescent quenching. (C) 2004 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000224847900012
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/55827]  
专题中国科学院化学研究所
通讯作者Chen, ZB
作者单位1.Shanxi Univ, Coll Chem & Chem Engn, Taiyuan 030006, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Feng, LH,Chen, ZB,Bai, FL. Photophysical processes of a fluorene derivative containing 1,3,4-oxadiazole[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2004,60(13):3029-3032.
APA Feng, LH,Chen, ZB,&Bai, FL.(2004).Photophysical processes of a fluorene derivative containing 1,3,4-oxadiazole.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,60(13),3029-3032.
MLA Feng, LH,et al."Photophysical processes of a fluorene derivative containing 1,3,4-oxadiazole".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 60.13(2004):3029-3032.

入库方式: OAI收割

来源:化学研究所

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