Photophysical processes of a fluorene derivative containing 1,3,4-oxadiazole
文献类型:期刊论文
作者 | Feng, LH; Chen, ZB; Bai, FL |
刊名 | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
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出版日期 | 2004-11-01 |
卷号 | 60期号:13页码:3029-3032 |
关键词 | Exciplex Fullerene (C-60) Carbon Nanotubes (Cnts) 2-Phenyl-5-[3 '-(Methacrylamido)Phenyl]-1 9 3 9-bis(4 '-aminophenyl)Fluorene 4-oxadiazole |
ISSN号 | 1386-1425 |
DOI | 10.1016/j.saa.2004.02.019 |
英文摘要 | The photophysical processes of 9,9-bis{4'-[2"-phenyl-5"-(3"'-(methacryl-amido)phenyl)]- 1",3",4"-oxadiazolylphenyl}fluorene (F-MAOP) formed by Heck reaction of 9,9-bis(4'-iodophenyl)fluorene (F-IP) and 2-phenyl-5-[3'-(methacrylamido)phenyl]-1,3,4-oxadiazole (OXD) have been carefully studied. The results show that the compound emits blue and blue-violet light and the emission spectra exhibit obvious solvent effect. With the increase of polarity of solvents, the fluorescence spectra change obviously and appear blue shift at room temperature. In addition, the light-emitting can be quenched by both electron donor (N,N-dimethylaniline, DMA) and electron acceptor (C-60). When N,N-dimethylaniline is gradually added into the solution of F-MAOP, the emission intensities of fluorescence are unusually increased. But when the concentration of DMA beyond a certain scope, the emission intensities of fluorescence are gradually decreased. The dimolecular exciplex between F-MAOP and C-60 are formed and the quenching effect follows the Stern-Volmer equation. Moreover, interaction between F-MAOP and carbon nanotubes (CNTs) is also studied by fluorescent quenching. (C) 2004 Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000224847900012 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/55827] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Chen, ZB |
作者单位 | 1.Shanxi Univ, Coll Chem & Chem Engn, Taiyuan 030006, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Feng, LH,Chen, ZB,Bai, FL. Photophysical processes of a fluorene derivative containing 1,3,4-oxadiazole[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2004,60(13):3029-3032. |
APA | Feng, LH,Chen, ZB,&Bai, FL.(2004).Photophysical processes of a fluorene derivative containing 1,3,4-oxadiazole.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,60(13),3029-3032. |
MLA | Feng, LH,et al."Photophysical processes of a fluorene derivative containing 1,3,4-oxadiazole".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 60.13(2004):3029-3032. |
入库方式: OAI收割
来源:化学研究所
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