Organolanthanides with 3-(2-pyridylmethyl) indenyl ligands: synthesis, crystal structures and catalytic activities of divalent complexes for epsilon-caprolactone polymerization
文献类型：期刊论文
| 作者 | Cheng, JH; Cui, DM; Chen, WQ; Hu, NH; Tang, T; Huang, BT |
| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2004-08-15 |
| 卷号 | 689期号:16页码:2646-2653 |
| 关键词 | 3-(2-pyridylmethyl) Indenyl Divalent Lanthanides Crystal Structure Epsilon-caprolactone |
| ISSN号 | 0022-328X |
| DOI | 10.1016/j.jorganchem.2004.05.030 |
| 英文摘要 | Reaction of 3-(2-pyridylmethyl)indenyl lithium (1) with LnI(2)(THF)(2) (Ln = Sm, Yb) in THF produced the divalent organolanthanides (C5H4NCH2C9H6)(2)Ln(II)(THF) (Ln = Sm (2), Yb (3)) in high yield. 1 reacts with LnCl(3) (Ln = Nd, Sm, Yb) in THF to give bis(3-(2-pyridylmethyl)indenyl) lanthanide chlorides (C5H4NCH2C9H6)(2)Ln(III)Cl (Ln = Nd (4), Sm (5)) and the unexpected divalent lanthanides 3 (Ln = Yb). Complexes 2-5 show more stable in air than the non-functionalized analogues. X-ray structural analyses of 2-4 were performed. 2 and 3 belong to the high symmetrical space group (Cmcm) with the same structures, they are THF-solvated 9-coordinate monomeric in the solid state, while 4 is an unsolvated 9-coordinate monomer with a trans arrangement of both the side-arms and indenyl rings in the solid state. Additionally, 2 and 3 show moderate polymerization activities for F-caprolactone (CL). (C) 2004 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000223386200011 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55829]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, T |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, JH,Cui, DM,Chen, WQ,et al. Organolanthanides with 3-(2-pyridylmethyl) indenyl ligands: synthesis, crystal structures and catalytic activities of divalent complexes for epsilon-caprolactone polymerization[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2004,689(16):2646-2653. |
| APA | Cheng, JH,Cui, DM,Chen, WQ,Hu, NH,Tang, T,&Huang, BT.(2004).Organolanthanides with 3-(2-pyridylmethyl) indenyl ligands: synthesis, crystal structures and catalytic activities of divalent complexes for epsilon-caprolactone polymerization.JOURNAL OF ORGANOMETALLIC CHEMISTRY,689(16),2646-2653. |
| MLA | Cheng, JH,et al."Organolanthanides with 3-(2-pyridylmethyl) indenyl ligands: synthesis, crystal structures and catalytic activities of divalent complexes for epsilon-caprolactone polymerization".JOURNAL OF ORGANOMETALLIC CHEMISTRY 689.16(2004):2646-2653. |
入库方式： OAI收割
来源：化学研究所
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