High pressure effect on spectroscopy properties of sandwich-like europium bis[2,3,9,10,16,17,23,24-octakis(4-methoxyphenoxy)phthalocyninatol]
文献类型：期刊论文
| 作者 | Fan, JF; Li, H; He, LM; Xiong, F; Li, SY; Wang, SQ; Shen, SY; Xu, HJ; Yang, GQ |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2004-01-14 |
| 卷号 | 62期号:1页码:37-41 |
| 关键词 | Sandwich-like Metal Phthalocynine High Pressure Effect Photophysical Process |
| ISSN号 | 0567-7351 |
| 英文摘要 | Spectroscopic properties of a sandwich-like metal phthalocynine, europium bis[2,3,9,10,16,17,23,24-octakis(4-methoxyphenoxy)phthalocyninato], have been studied at different pressures. The pressure tuning effect has been observed in the absorption of the Q band for the complex. With increase of pressure, the LUMO and SUMO ( Second Unoccupied Molecular Orbit) of the complex are stabilized to lower level. It increases the energy gap between the LUMO (or SUMO) and the higher energy level, which corresponds to the absorption of the Sorel band of the complex. This enhancement of the energy gap slows down the radiationless internal conversion of the electron that has been excited to the higher energy level by the Sorel absorption. Thus obvious increase of the emission by the Sorel absorption has been observed with increase of pressure. |
| 语种 | 英语 |
| WOS记录号 | WOS:000187998100008 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55871]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fan, JF |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, JF,Li, H,He, LM,et al. High pressure effect on spectroscopy properties of sandwich-like europium bis[2,3,9,10,16,17,23,24-octakis(4-methoxyphenoxy)phthalocyninatol][J]. ACTA CHIMICA SINICA,2004,62(1):37-41. |
| APA | Fan, JF.,Li, H.,He, LM.,Xiong, F.,Li, SY.,...&Yang, GQ.(2004).High pressure effect on spectroscopy properties of sandwich-like europium bis[2,3,9,10,16,17,23,24-octakis(4-methoxyphenoxy)phthalocyninatol].ACTA CHIMICA SINICA,62(1),37-41. |
| MLA | Fan, JF,et al."High pressure effect on spectroscopy properties of sandwich-like europium bis[2,3,9,10,16,17,23,24-octakis(4-methoxyphenoxy)phthalocyninatol]".ACTA CHIMICA SINICA 62.1(2004):37-41. |
入库方式： OAI收割
来源：化学研究所
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