Effect of PEO-PPO-PEO structure on the compressed ethylene-induced reverse micelle formation and water solubilization
文献类型：期刊论文
| 作者 | Zhang, R; Liu, J; Han, BX; Wang, B; Sun, DH; He, J |
| 刊名 | POLYMER
 |
| 出版日期 | 2005-05-11 |
| 卷号 | 46期号:11页码:3936-3941 |
| 关键词 | Reverse Micelle Surfactant Structure Peo-ppo-peo |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.poplymer.2005.02.105 |
| 英文摘要 | Some of the poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) (PEO-PPO-PEO) tri-block copolymers aggregate in pxylene upon addition of ethylene and form reverse micelles at higher temperature at which the reverse micelles cannot be formed without addition of compressed ethylene. An abrupt increase of water solubilization is observed at a certain ethylene pressure. The effects of surfactant structure, such as the ratio of EO (EO weight percent) and the molecular mass, on the copolymer micellization and the solubilization of water in such systems are studied. For the copolymers with the same length of PO block, higher EO ratios facilitate the reverse micelle formation. However, as the EO ratio reaches 70%, it cannot form reverse micelles because the hydrophilicity is too high. For the copolymers with same composition, higher molecular weight is favorable to forming the reverse micelle due to the hydrophilic and folding effects, respectively. The reverse micelle solution can solubilize water with W-0 (molar ratio of water to EO segment) up to 4.1. © 2005 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000229051200043 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55917]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, BX |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, R,Liu, J,Han, BX,et al. Effect of PEO-PPO-PEO structure on the compressed ethylene-induced reverse micelle formation and water solubilization[J]. POLYMER,2005,46(11):3936-3941. |
| APA | Zhang, R,Liu, J,Han, BX,Wang, B,Sun, DH,&He, J.(2005).Effect of PEO-PPO-PEO structure on the compressed ethylene-induced reverse micelle formation and water solubilization.POLYMER,46(11),3936-3941. |
| MLA | Zhang, R,et al."Effect of PEO-PPO-PEO structure on the compressed ethylene-induced reverse micelle formation and water solubilization".POLYMER 46.11(2005):3936-3941. |
入库方式： OAI收割
来源：化学研究所
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