Self-organization of a self-assembled supramolecular rectangle, square, and three-dimensional cage on Au(111) surfaces
文献类型:期刊论文
作者 | Yuan, QH; Wan, LJ; Jude, H; Stang, PJ |
刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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出版日期 | 2005-11-23 |
卷号 | 127期号:46页码:16279-16286 |
ISSN号 | 0002-7863 |
DOI | 10.1021/ja0549300 |
英文摘要 | The structure and conformation of three self-assembled supramolecular species, a rectangle, a square, and a three-dimensional cage, on Au(111) surfaces were investigated by scanning tunneling microscopy. These supramolecular assemblies adsorb on Au(1 11) surfaces and self-organize to form highly ordered adlayers with distinct conformations that are consistent with their chemical structures. The faces of the supramolecular rectangle and square lie flat on the surface, preserving their rectangle and square conformations, respectively. The three-dimensional cage also forms well-ordered adlayers on the gold surface, forming regular molecular rows of assemblies. When the rectangle and cage were mixed together, the assemblies separated into individual domains, and no mixed adlayers were observed. These results provide direct evidence of the noncrystalline solid-state structures of these assemblies and information about how they self-organize on Au(111) surfaces, which is of importance in the potential manufacturing of functional nanostructures and devices. |
语种 | 英语 |
WOS记录号 | WOS:000233445900058 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/55923] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wan, LJ |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA |
推荐引用方式 GB/T 7714 | Yuan, QH,Wan, LJ,Jude, H,et al. Self-organization of a self-assembled supramolecular rectangle, square, and three-dimensional cage on Au(111) surfaces[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2005,127(46):16279-16286. |
APA | Yuan, QH,Wan, LJ,Jude, H,&Stang, PJ.(2005).Self-organization of a self-assembled supramolecular rectangle, square, and three-dimensional cage on Au(111) surfaces.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,127(46),16279-16286. |
MLA | Yuan, QH,et al."Self-organization of a self-assembled supramolecular rectangle, square, and three-dimensional cage on Au(111) surfaces".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 127.46(2005):16279-16286. |
入库方式: OAI收割
来源:化学研究所
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