Highly enantioselective iridium-catalyzed hydrogenation of quinoline derivatives using chiral phosphinite H8-BINAPO
文献类型：期刊论文
| 作者 | Lam, KH; Xu, LJ; Feng, LC; Fan, QH; Lam, FL; Lo, WH; Chan, ASC |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2005-11-01 |
| 卷号 | 347期号:14页码:1755-1758 |
| 关键词 | Asymmetric Hydrogenation Immobilization Iridium Phosphinite Ligands Poly(Ethylene Glycol) Dimethyl Ether Quinoline |
| ISSN号 | 1615-4150 |
| DOI | 10.1002/adsc.200505130 |
| 英文摘要 | The chiral diphosphinite H8-BINAPO derived from H8-BINOL has been used in the Ir-catalyzed asymmetric hydrogenation of quinolines, and high enantioselectivity (up to 97% ee) was obtained. Immobilization of the iridium catalyst in poly(ethylene glycol) dimethyl ether (DMPEG) is also discussed. With DMPEG/hexane biphasic system, better enantioselectivities were obtained as compared to those observed in aprotic organic solvents. |
| 语种 | 英语 |
| WOS记录号 | WOS:000233483000004 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/55939]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Fan, QH |
| 作者单位 | 1.Hong Kong Polytech Univ, Open Lab Chirotechnol, Inst Mol Technol Drug Discovery & Synth, Hong Kong, Hong Kong, Peoples R China 2.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lam, KH,Xu, LJ,Feng, LC,et al. Highly enantioselective iridium-catalyzed hydrogenation of quinoline derivatives using chiral phosphinite H8-BINAPO[J]. ADVANCED SYNTHESIS & CATALYSIS,2005,347(14):1755-1758. |
| APA | Lam, KH.,Xu, LJ.,Feng, LC.,Fan, QH.,Lam, FL.,...&Chan, ASC.(2005).Highly enantioselective iridium-catalyzed hydrogenation of quinoline derivatives using chiral phosphinite H8-BINAPO.ADVANCED SYNTHESIS & CATALYSIS,347(14),1755-1758. |
| MLA | Lam, KH,et al."Highly enantioselective iridium-catalyzed hydrogenation of quinoline derivatives using chiral phosphinite H8-BINAPO".ADVANCED SYNTHESIS & CATALYSIS 347.14(2005):1755-1758. |
入库方式： OAI收割
来源：化学研究所
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