Multi-functional polypyrrole nanofibers via a functional dopant-introduced process
文献类型：期刊论文
| 作者 | Huang, K; Wan, MX; Long, YZ; Chen, ZJ; Wei, Y |
| 刊名 | SYNTHETIC METALS
 |
| 出版日期 | 2005-12-15 |
| 卷号 | 155期号:3页码:495-500 |
| 关键词 | Multi-functionality Dopant-introduced Polypyrrole Nanofibers And Micelles |
| ISSN号 | 0379-6779 |
| DOI | 10.1016/j.synthmet.2005.06.013 |
| 英文摘要 | This paper reports a functional dopant-introduced route to synthesize polypyrrole (PPy) nanofibers (60-100 nm in average diameter) in the presence of p-hydroxyl-azobenzene sulfonic acid (p-OH-ABSA) as a functional dopant. The nanofibers show a high conductivity (120-130 S/cm) and photoisomerization, which resulted from proton doping and photoisomerization of azobenzene moiety, respectively. Static and dynamic light scattering as well as freeze-fracture replication transmission electron microscope measurements (FFRTEM) showed that the self-assembled cylindrical micelles act as "soft-templates" during the formation of the nanofibers. Influence of polymerization conditions, such as the type of oxidant, the rate of oxidant addition, the concentration of reactants and polymerization time, on the fibrous morphology of PPy-(p-OH-ABSA) has been investigated. The characterizations of molecular structure, photoisomerization and electrical properties have been carried out. The method described in this study provides a simple and inexpensive route to prepare multi-functional nano-structured conducting polymers. (C) 2005 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000234185700010 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/56057]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan, MX |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solid Lab, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Phys, Lab Extreme Condit Phys, Beijing 100080, Peoples R China 3.Drexel Univ, Dept Chem, Philadelphia, PA 19104 USA |
| 推荐引用方式 GB/T 7714 | Huang, K,Wan, MX,Long, YZ,et al. Multi-functional polypyrrole nanofibers via a functional dopant-introduced process[J]. SYNTHETIC METALS,2005,155(3):495-500. |
| APA | Huang, K,Wan, MX,Long, YZ,Chen, ZJ,&Wei, Y.(2005).Multi-functional polypyrrole nanofibers via a functional dopant-introduced process.SYNTHETIC METALS,155(3),495-500. |
| MLA | Huang, K,et al."Multi-functional polypyrrole nanofibers via a functional dopant-introduced process".SYNTHETIC METALS 155.3(2005):495-500. |
入库方式： OAI收割
来源：化学研究所
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