Synthesis and characterization of a novel reactive oligomeric ladderlike copolymethyl-aminopropyl silsesquioxane
文献类型：期刊论文
| 作者 | Duan, QH; Zhang, TY; Deng, KL; Xie, P; Zhang, RB |
| 刊名 | CHINESE JOURNAL OF POLYMER SCIENCE
 |
| 出版日期 | 2005-07-01 |
| 卷号 | 23期号:4页码:355-361 |
| 关键词 | Ladderlike Polyorganosilsesquioxane (Lps) Self-assembly Stepwise Coupling Polymerization (Scp) Hydrosilylation |
| ISSN号 | 0256-7679 |
| 英文摘要 | A novel ordered reactive oligomeric ladderlike copolymethyl-aminopropylsilsesquioxane (Me-AP-T), was successfully synthesized by an efficient hydrosilylation graft reaction of 1,1,1-trimethyl-N-2-propenyl-silanamine with a reactive oligomeric ladderlike copolymethyl-hydrosilsesquioxane (Me-H-T), which was prepared by "supramolecular chemistry-dictated stepwise coupling polymerization" process. FT-IR, H-1- and Si-29-NMR spectra show that hydrosilylation reaction proceeds completely. Moreover, H-1-NMR spectra also indicate that both the molar ratios of equivalent to SiMe group to Si-H and equivalent to SiMe group to equivalent to SiPrNH2 are approximately 1:1 respectively based on the ratio of integrated resonance areas of the different groups. XRD analysis and Si-29-NMR spectra are used for investigating the ladderlike structure of the polymers. A high T-g (128.38 degrees C) of Me-AP-T shown in DSC measurement implies that the ordered reactive Me-AP-T macromolecules have much stiff chains. |
| 语种 | 英语 |
| WOS记录号 | WOS:000230728800002 |
| 出版者 | SPRINGER HEIDELBERG |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/56065]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, RB |
| 作者单位 | Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Joint Lab Polymer Sci & Mat, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Duan, QH,Zhang, TY,Deng, KL,et al. Synthesis and characterization of a novel reactive oligomeric ladderlike copolymethyl-aminopropyl silsesquioxane[J]. CHINESE JOURNAL OF POLYMER SCIENCE,2005,23(4):355-361. |
| APA | Duan, QH,Zhang, TY,Deng, KL,Xie, P,&Zhang, RB.(2005).Synthesis and characterization of a novel reactive oligomeric ladderlike copolymethyl-aminopropyl silsesquioxane.CHINESE JOURNAL OF POLYMER SCIENCE,23(4),355-361. |
| MLA | Duan, QH,et al."Synthesis and characterization of a novel reactive oligomeric ladderlike copolymethyl-aminopropyl silsesquioxane".CHINESE JOURNAL OF POLYMER SCIENCE 23.4(2005):355-361. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。