Studies on dynamic surface tension of an outstanding microemulsifier in supercritical CO2 and its wetting performance
文献类型:期刊论文
作者 | Gao, YN; Wang, ZN; Hou, WG; Li, GZ; Han, BX; Zhang, GY |
刊名 | JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
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出版日期 | 2005 |
卷号 | 26期号:6页码:745-751 |
关键词 | Dynamic Surface Tension Wetting Parameters Maximum Bubble Pressure |
ISSN号 | 0193-2691 |
DOI | 10.1081/DIS-200063069 |
英文摘要 | Dodecyl polyoxyethylene( 4) polyoxypropylene( 5) ether (LS45) is an outstanding microemulsifier in supercritical CO2. The dynamic surface tension (DST) of this nonionic surfactant was investigated by using the maximum bubble pressure instrument. The effects of concentration and temperature on DST parameters (n, t(i), t*, t(m), and R-1/2) and its adsorption mechanism were discussed by Rosen's empirical equation and the asymptotic Ward and Tordai equation for the LS45 solution system. Finally, the parameters at 1 s related to Draves's wetting performance, pC(20(1s)), C-1s (i)*, and C-1s*, analyzed. The results showed that were with increase of bulk concentration and temperature, dynamic surface activity increased. Parameters at 1 s indicated that LS45 is of high surface activity and a very good wetting agent. One-second related parameters, C-1s (i)* and C-1s*, are valuable in the treatment of practical applications of surfactants. Optimum wetting can be expected at the concentration of 4.8 x 10(-4) mol/dm(3) for LS45 solution. |
语种 | 英语 |
WOS记录号 | WOS:000231371000014 |
出版者 | TAYLOR & FRANCIS INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/56133] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Li, GZ |
作者单位 | 1.Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 3.China Res Inst Daily Chem Ind, Taiyuan, Peoples R China |
推荐引用方式 GB/T 7714 | Gao, YN,Wang, ZN,Hou, WG,et al. Studies on dynamic surface tension of an outstanding microemulsifier in supercritical CO2 and its wetting performance[J]. JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY,2005,26(6):745-751. |
APA | Gao, YN,Wang, ZN,Hou, WG,Li, GZ,Han, BX,&Zhang, GY.(2005).Studies on dynamic surface tension of an outstanding microemulsifier in supercritical CO2 and its wetting performance.JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY,26(6),745-751. |
MLA | Gao, YN,et al."Studies on dynamic surface tension of an outstanding microemulsifier in supercritical CO2 and its wetting performance".JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY 26.6(2005):745-751. |
入库方式: OAI收割
来源:化学研究所
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