中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Studies on dynamic surface tension of an outstanding microemulsifier in supercritical CO2 and its wetting performance

文献类型:期刊论文

作者Gao, YN; Wang, ZN; Hou, WG; Li, GZ; Han, BX; Zhang, GY
刊名JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
出版日期2005
卷号26期号:6页码:745-751
关键词Dynamic Surface Tension Wetting Parameters Maximum Bubble Pressure
ISSN号0193-2691
DOI10.1081/DIS-200063069
英文摘要Dodecyl polyoxyethylene( 4) polyoxypropylene( 5) ether (LS45) is an outstanding microemulsifier in supercritical CO2. The dynamic surface tension (DST) of this nonionic surfactant was investigated by using the maximum bubble pressure instrument. The effects of concentration and temperature on DST parameters (n, t(i), t*, t(m), and R-1/2) and its adsorption mechanism were discussed by Rosen's empirical equation and the asymptotic Ward and Tordai equation for the LS45 solution system. Finally, the parameters at 1 s related to Draves's wetting performance, pC(20(1s)), C-1s (i)*, and C-1s*, analyzed. The results showed that were with increase of bulk concentration and temperature, dynamic surface activity increased. Parameters at 1 s indicated that LS45 is of high surface activity and a very good wetting agent. One-second related parameters, C-1s (i)* and C-1s*, are valuable in the treatment of practical applications of surfactants. Optimum wetting can be expected at the concentration of 4.8 x 10(-4) mol/dm(3) for LS45 solution.
语种英语
WOS记录号WOS:000231371000014
出版者TAYLOR & FRANCIS INC
源URL[http://ir.iccas.ac.cn/handle/121111/56133]  
专题中国科学院化学研究所
通讯作者Li, GZ
作者单位1.Shandong Univ, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
3.China Res Inst Daily Chem Ind, Taiyuan, Peoples R China
推荐引用方式
GB/T 7714
Gao, YN,Wang, ZN,Hou, WG,et al. Studies on dynamic surface tension of an outstanding microemulsifier in supercritical CO2 and its wetting performance[J]. JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY,2005,26(6):745-751.
APA Gao, YN,Wang, ZN,Hou, WG,Li, GZ,Han, BX,&Zhang, GY.(2005).Studies on dynamic surface tension of an outstanding microemulsifier in supercritical CO2 and its wetting performance.JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY,26(6),745-751.
MLA Gao, YN,et al."Studies on dynamic surface tension of an outstanding microemulsifier in supercritical CO2 and its wetting performance".JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY 26.6(2005):745-751.

入库方式: OAI收割

来源:化学研究所

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