Local conformations of poly(vinyl methyl ether)
文献类型：期刊论文
| 作者 | Zeng, XG; Chen, L; Yang, XZ |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2005-08-10 |
| 卷号 | 26期号:8页码:1561-1564 |
| 关键词 | Poly(Vinyl Methyl Ether) Side-group Orientation Conformational Energy Characteristic Ratio |
| ISSN号 | 0251-0790 |
| 英文摘要 | A full-relaxation optimization of molecular structure and the Dreiding I force field are, employed to obtain the geometry parameters and the conformational energies of meso and racemic dyad of poly (vinyl methyl ether) (PVME). It is found in this study that three different side-group orientations result in different energetic contour maps. A reasonable RIS model of PVME has thus been built up based on the statistical average of the energies from the three different orientation models. The characteristic ratio of PVME calculated was found to be agreement with the experiment result. Therefore, considering the orientation of side-group allows us to satisfactorily reproduce the experimental dimensions of random PVME chain. |
| 语种 | 英语 |
| WOS记录号 | WOS:000231321400042 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/56173]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, XZ |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zeng, XG,Chen, L,Yang, XZ. Local conformations of poly(vinyl methyl ether)[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2005,26(8):1561-1564. |
| APA | Zeng, XG,Chen, L,&Yang, XZ.(2005).Local conformations of poly(vinyl methyl ether).CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,26(8),1561-1564. |
| MLA | Zeng, XG,et al."Local conformations of poly(vinyl methyl ether)".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 26.8(2005):1561-1564. |
入库方式： OAI收割
来源：化学研究所
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