Studies on the reactive polyvinylidene fluoride-polyamide 6 interfaces: rheological properties and interfacial width
文献类型：期刊论文
| 作者 | Wu, Y; Yu, XB; Yang, YM; Li, BY; Han, YC |
| 刊名 | POLYMER
 |
| 出版日期 | 2005-03-10 |
| 卷号 | 46期号:7页码:2365-2371 |
| 关键词 | Grafting Functionalization Rheology Ellipsometer |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2005.01.048 |
| 英文摘要 | We firstly synthesized and characterized a series of functional carboxylated polyvinylidene fluoride (PVDF-g-AAc). Then the temporal change of the complex viscosity (eta*) of the two plates consisting of the graft polymer PVDF-g-AAe and polyamide 6 (PA6) was measured by a rotational rheometer, There were two distinct stages for the change of the complex viscosity (eta*) with time: (i) stage 1, where eta* increased rapidly at short times, a reaction-controlled kinetics was induced; (ii) stage II, where eta* increased slowly at a long time, however, a diffusion-controlled kinetics was obtained. Despite whether the kinetics are reaction -controlled or diffusion-controlled, the reaction could be predicted by pseudo-first-order kinetics. Meanwhile, the reaction temperature had an effect on the interfacial width and roughness. The value of the interfacial root-mean-square (rms) roughness obtained from AFM was consistent with that of the interfacial width from ellipsometer at different temperatures. (c) 2005 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000227654500039 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/56249]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, YC |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Y,Yu, XB,Yang, YM,et al. Studies on the reactive polyvinylidene fluoride-polyamide 6 interfaces: rheological properties and interfacial width[J]. POLYMER,2005,46(7):2365-2371. |
| APA | Wu, Y,Yu, XB,Yang, YM,Li, BY,&Han, YC.(2005).Studies on the reactive polyvinylidene fluoride-polyamide 6 interfaces: rheological properties and interfacial width.POLYMER,46(7),2365-2371. |
| MLA | Wu, Y,et al."Studies on the reactive polyvinylidene fluoride-polyamide 6 interfaces: rheological properties and interfacial width".POLYMER 46.7(2005):2365-2371. |
入库方式： OAI收割
来源：化学研究所
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