Phase Transition in Solid Co-3
文献类型:期刊论文
作者 | Xu Zhijin; Yan Jimin |
刊名 | ACTA PHYSICO-CHIMICA SINICA
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出版日期 | 1995 |
卷号 | 11期号:11页码:991-996 |
关键词 | C-60 Phase Transition (Exp 6 1) Potential Model Orientational Transition |
ISSN号 | 1000-6818 |
DOI | 10.3866/PKU.WHXB19951107 |
英文摘要 | The. interactions between C,v, molecules in solid state are calculated by the pot cola] model)del (ex-p 6 1). The states of C-60, molecules in solid are given at room temperature and at lower temperature C-60 molecule rotates rapidly at room temperature: the rotation rate decreases and the rotational axes tend to ordering as temperature becomes lower. And at about 260K the structure undergoes a first-order phase transiton from the high-temperature FCC phase to the ordered SC structure. The molecule equivalence above 260K is now broken by rotating the four molecules through the same angle but around different < 111 > axes: the molecule at (0,0,0) around [111, that at (1/2,1/2,0) around [1 (11) over bar], that at (0,1/2,1/2) around 111] and at (1/2,0,1/2) around [(11) over bar1]. At about 90K the system undergoes a second order phase tranistion glass transition. |
语种 | 英语 |
WOS记录号 | WOS:000207591000007 |
出版者 | PEKING UNIV PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/56327] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Xu Zhijin |
作者单位 | Acad Sinica, Inst Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Xu Zhijin,Yan Jimin. Phase Transition in Solid Co-3[J]. ACTA PHYSICO-CHIMICA SINICA,1995,11(11):991-996. |
APA | Xu Zhijin,&Yan Jimin.(1995).Phase Transition in Solid Co-3.ACTA PHYSICO-CHIMICA SINICA,11(11),991-996. |
MLA | Xu Zhijin,et al."Phase Transition in Solid Co-3".ACTA PHYSICO-CHIMICA SINICA 11.11(1995):991-996. |
入库方式: OAI收割
来源:化学研究所
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