Effect of poly(vinyl acetate) (PVAc) on thermal behavior and mechanical properties of poly(3-hydroxybutyrate)/poly(propylene carbonate) (PHB/PPC) blends
文献类型：期刊论文
| 作者 | Wang, XY; Peng, SW; Dong, LS |
| 刊名 | COLLOID AND POLYMER SCIENCE
 |
| 出版日期 | 2005-11-01 |
| 卷号 | 284期号:2页码:167-174 |
| 关键词 | Poly(3-hydroxybutyrate) Poly(Propylene Carbonate) Poly(Vinyl Acetate) Compatibilizer |
| ISSN号 | 0303-402X |
| DOI | 10.1007/s00396-005-1353-y |
| 英文摘要 | To assess the compatibility of blends of synthetic polypropylene carbonate) (PPC), with a natural bacterial poly(3-hydroxybutyrate) (PHB), a simple casting procedure of blend was used. poly(3-hydroxybutyrate)/poly(propylene carbonate) blends are found to be incompatible according to DSC and DMA analysis. In order to improve the compatibility and mechanical properties of PHB/PPC blends, poly(vinyl acetate) (PVAc) was added as a compatibilizer. The effects of PVAc on the thermal behavior, morphology, and mechanical properties of 70PHB/30PPC blend were investigated. The results show that the melting point and the crystallization temperature of PHB in blends decrease with the increase of PVAc content in blends, the loss factor changes from two separate peaks of 70PHB/30PPC blend to one peak of 70PHB/30PPC/12PVAc blend. It is also found that adding PVAc into 70PHB/30PPC blend can decrease the size of dispersed phase from morphology analysis. The result of tensile properties shows that PVAc can increase the tensile strength and Young's modulus of 70PHB/30PPC blend, and both the elongation at break and the tensile toughness increase significantly with PVAc added into 70PHB/30PPC. |
| 语种 | 英语 |
| WOS记录号 | WOS:000233600300007 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/56337]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, XY |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, XY,Peng, SW,Dong, LS. Effect of poly(vinyl acetate) (PVAc) on thermal behavior and mechanical properties of poly(3-hydroxybutyrate)/poly(propylene carbonate) (PHB/PPC) blends[J]. COLLOID AND POLYMER SCIENCE,2005,284(2):167-174. |
| APA | Wang, XY,Peng, SW,&Dong, LS.(2005).Effect of poly(vinyl acetate) (PVAc) on thermal behavior and mechanical properties of poly(3-hydroxybutyrate)/poly(propylene carbonate) (PHB/PPC) blends.COLLOID AND POLYMER SCIENCE,284(2),167-174. |
| MLA | Wang, XY,et al."Effect of poly(vinyl acetate) (PVAc) on thermal behavior and mechanical properties of poly(3-hydroxybutyrate)/poly(propylene carbonate) (PHB/PPC) blends".COLLOID AND POLYMER SCIENCE 284.2(2005):167-174. |
入库方式： OAI收割
来源：化学研究所
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