中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Atomic force microscopy study of the lamellar growth of isotactic polypropylene

文献类型:期刊论文

作者Zhou, JJ; Liu, JG; Yan, SK; Dong, JY; Li, L; Chan, CM; Schultz, JM
刊名POLYMER
出版日期2005-05-26
卷号46期号:12页码:4077-4087
关键词Crystallization Lamellar Growth Atomic Force Microscopy
ISSN号0032-3861
DOI10.1016/j.polymer.2005.03.047
英文摘要The growth behaviors of cross-hatched and lath-like lamellae of α-form spherulites and flat-on lamellae of β-form pherulites of isotactic polypropylene were studied with a high-temperature atomic force microscopy in situ and in real time. The growth rates of crystal lamellae in types I, II and mixed α-form spherulites and in β-form spherulites, as well as the spatial frequency of tangential branching, were measured. The frequency of tangential branching increases with decreasing crystallization temperature, while the growth rates of leading radial and tangential lamellae are approximately the sane at a given temperature. Observations of as-crystallized materials demonstrated that the spacing and length of transverse lamellae is sufficient to differentiate among spherulite types. Height measurements in the melt near the growth surface indicate roles of molecular transport in the crystallization process. © 2005 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000229598400014
出版者ELSEVIER SCI LTD
源URL[http://ir.iccas.ac.cn/handle/121111/56349]  
专题中国科学院化学研究所
通讯作者Li, L
作者单位1.Hong Kong Univ Sci & Technol, Dept Chem Engn, Hong Kong, Hong Kong, Peoples R China
2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys, Beijing 100080, Peoples R China
3.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China
4.Univ Delaware, Dept Chem Engn, Newark, DE 19716 USA
推荐引用方式
GB/T 7714
Zhou, JJ,Liu, JG,Yan, SK,et al. Atomic force microscopy study of the lamellar growth of isotactic polypropylene[J]. POLYMER,2005,46(12):4077-4087.
APA Zhou, JJ.,Liu, JG.,Yan, SK.,Dong, JY.,Li, L.,...&Schultz, JM.(2005).Atomic force microscopy study of the lamellar growth of isotactic polypropylene.POLYMER,46(12),4077-4087.
MLA Zhou, JJ,et al."Atomic force microscopy study of the lamellar growth of isotactic polypropylene".POLYMER 46.12(2005):4077-4087.

入库方式: OAI收割

来源:化学研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。