Atomic force microscopy study of the lamellar growth of isotactic polypropylene
文献类型:期刊论文
作者 | Zhou, JJ; Liu, JG; Yan, SK; Dong, JY; Li, L; Chan, CM; Schultz, JM |
刊名 | POLYMER
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出版日期 | 2005-05-26 |
卷号 | 46期号:12页码:4077-4087 |
关键词 | Crystallization Lamellar Growth Atomic Force Microscopy |
ISSN号 | 0032-3861 |
DOI | 10.1016/j.polymer.2005.03.047 |
英文摘要 | The growth behaviors of cross-hatched and lath-like lamellae of α-form spherulites and flat-on lamellae of β-form pherulites of isotactic polypropylene were studied with a high-temperature atomic force microscopy in situ and in real time. The growth rates of crystal lamellae in types I, II and mixed α-form spherulites and in β-form spherulites, as well as the spatial frequency of tangential branching, were measured. The frequency of tangential branching increases with decreasing crystallization temperature, while the growth rates of leading radial and tangential lamellae are approximately the sane at a given temperature. Observations of as-crystallized materials demonstrated that the spacing and length of transverse lamellae is sufficient to differentiate among spherulite types. Height measurements in the melt near the growth surface indicate roles of molecular transport in the crystallization process. © 2005 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000229598400014 |
出版者 | ELSEVIER SCI LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/56349] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Li, L |
作者单位 | 1.Hong Kong Univ Sci & Technol, Dept Chem Engn, Hong Kong, Hong Kong, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China 4.Univ Delaware, Dept Chem Engn, Newark, DE 19716 USA |
推荐引用方式 GB/T 7714 | Zhou, JJ,Liu, JG,Yan, SK,et al. Atomic force microscopy study of the lamellar growth of isotactic polypropylene[J]. POLYMER,2005,46(12):4077-4087. |
APA | Zhou, JJ.,Liu, JG.,Yan, SK.,Dong, JY.,Li, L.,...&Schultz, JM.(2005).Atomic force microscopy study of the lamellar growth of isotactic polypropylene.POLYMER,46(12),4077-4087. |
MLA | Zhou, JJ,et al."Atomic force microscopy study of the lamellar growth of isotactic polypropylene".POLYMER 46.12(2005):4077-4087. |
入库方式: OAI收割
来源:化学研究所
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