Transition metal complexes bearing 2,6-bis(imino)pyridyl: Synthesis, structure, ethylene polymerization/oligomerization studies
文献类型：期刊论文
| 作者 | Su, BY; Zhao, JS; Sun, WH |
| 刊名 | SCIENCE IN CHINA SERIES B-CHEMISTRY
 |
| 出版日期 | 2005-12-01 |
| 卷号 | 48页码:45-49 |
| 关键词 | Bis(Imino)Pyridine Transition Metal Complex Ethylene Polymerization/oligomerization Catalytic Activity |
| ISSN号 | 1006-9291 |
| DOI | 10.1360/04zb0106 |
| 英文摘要 | A series of new complexes {2,6-bis[1-((2-methyl-4-methoxyphenyl)imino)ethyl]pyridine}MCl2 [M=Fe(II) (2), Co(II) (3), Ni(II) (4), Cu(II) (5), Zn(II) (6)] have been synthesized. At 25 degrees C, using 500 equiv of methylaluminoxane (MAO), the activities of Fe(II), Co(II) catalysts can reach 4.02 x 10(6) g/mol-Fe center dot h center dot atm for ethylene polymerization and 3.98x10(5) g/mol-Co center dot h center dot atm for ethylene oligomerization. The effects of polymerization conditions such as reaction temperature, Al/M molar ratio and time on the activity of catalyst have been explored. |
| 语种 | 英语 |
| WOS记录号 | WOS:000235737500010 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/56769]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhao, JS |
| 作者单位 | 1.NW Univ Xian, Dept Chem, Xian 710069, Peoples R China 2.Chinese Acad Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Su, BY,Zhao, JS,Sun, WH. Transition metal complexes bearing 2,6-bis(imino)pyridyl: Synthesis, structure, ethylene polymerization/oligomerization studies[J]. SCIENCE IN CHINA SERIES B-CHEMISTRY,2005,48:45-49. |
| APA | Su, BY,Zhao, JS,&Sun, WH.(2005).Transition metal complexes bearing 2,6-bis(imino)pyridyl: Synthesis, structure, ethylene polymerization/oligomerization studies.SCIENCE IN CHINA SERIES B-CHEMISTRY,48,45-49. |
| MLA | Su, BY,et al."Transition metal complexes bearing 2,6-bis(imino)pyridyl: Synthesis, structure, ethylene polymerization/oligomerization studies".SCIENCE IN CHINA SERIES B-CHEMISTRY 48(2005):45-49. |
入库方式： OAI收割
来源：化学研究所
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