Molecular arrangement and recognition of a new bolaform cinnamic acid derivative in LB films
文献类型:期刊论文
作者 | Yan, Y; Guo, S; Xiong, W; Huang, JB; Li, ZC; Ma, JM |
刊名 | ACTA PHYSICO-CHIMICA SINICA
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出版日期 | 2005-05-01 |
卷号 | 21期号:5页码:550-555 |
关键词 | Bolaform Cinnamic Acid Derivative Langmuir-blodgett Films Photodimerization Molecular Arrangement Molecular Recognition |
ISSN号 | 1000-6818 |
DOI | 10.3866/PKU.WHXB20050518 |
英文摘要 | A bolaamphiphile containing cinnamic acid moiety, [4-(10-hydroxydecanyloxy)-10-hydroxydecanylcinnamate, abbreviated HDC], was synthesized and the LB films of HDC were studied. It was found from the results of pi-A isotherms that multilayers of HDC were formed at the air/water interface. The photoreaction of HDC in LB films induced by UV light was investigated with UV and IR measurements. Photodimerization also took place in the mixed LB films of HDC and 1,16-hexadecanediol. The spectra results showed that the HDC molecules assembled orderly due to the separated recognition of pi-pi interaction and the zigzag stacking of methylene groups. XRD studies indicated that bilayers formed in the LB films with a tilt angle of 58.8 degrees and 53.2 degrees before and after UV irradiation, respectively. A packing model of HDC was also proposed. |
语种 | 英语 |
WOS记录号 | WOS:000229305800018 |
出版者 | PEKING UNIV PRESS |
源URL | [http://ir.iccas.ac.cn/handle/121111/56803] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Huang, JB |
作者单位 | Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Yan, Y,Guo, S,Xiong, W,et al. Molecular arrangement and recognition of a new bolaform cinnamic acid derivative in LB films[J]. ACTA PHYSICO-CHIMICA SINICA,2005,21(5):550-555. |
APA | Yan, Y,Guo, S,Xiong, W,Huang, JB,Li, ZC,&Ma, JM.(2005).Molecular arrangement and recognition of a new bolaform cinnamic acid derivative in LB films.ACTA PHYSICO-CHIMICA SINICA,21(5),550-555. |
MLA | Yan, Y,et al."Molecular arrangement and recognition of a new bolaform cinnamic acid derivative in LB films".ACTA PHYSICO-CHIMICA SINICA 21.5(2005):550-555. |
入库方式: OAI收割
来源:化学研究所
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