中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Molecular arrangement and recognition of a new bolaform cinnamic acid derivative in LB films

文献类型:期刊论文

作者Yan, Y; Guo, S; Xiong, W; Huang, JB; Li, ZC; Ma, JM
刊名ACTA PHYSICO-CHIMICA SINICA
出版日期2005-05-01
卷号21期号:5页码:550-555
关键词Bolaform Cinnamic Acid Derivative Langmuir-blodgett Films Photodimerization Molecular Arrangement Molecular Recognition
ISSN号1000-6818
DOI10.3866/PKU.WHXB20050518
英文摘要A bolaamphiphile containing cinnamic acid moiety, [4-(10-hydroxydecanyloxy)-10-hydroxydecanylcinnamate, abbreviated HDC], was synthesized and the LB films of HDC were studied. It was found from the results of pi-A isotherms that multilayers of HDC were formed at the air/water interface. The photoreaction of HDC in LB films induced by UV light was investigated with UV and IR measurements. Photodimerization also took place in the mixed LB films of HDC and 1,16-hexadecanediol. The spectra results showed that the HDC molecules assembled orderly due to the separated recognition of pi-pi interaction and the zigzag stacking of methylene groups. XRD studies indicated that bilayers formed in the LB films with a tilt angle of 58.8 degrees and 53.2 degrees before and after UV irradiation, respectively. A packing model of HDC was also proposed.
语种英语
WOS记录号WOS:000229305800018
出版者PEKING UNIV PRESS
源URL[http://ir.iccas.ac.cn/handle/121111/56803]  
专题中国科学院化学研究所
通讯作者Huang, JB
作者单位Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Yan, Y,Guo, S,Xiong, W,et al. Molecular arrangement and recognition of a new bolaform cinnamic acid derivative in LB films[J]. ACTA PHYSICO-CHIMICA SINICA,2005,21(5):550-555.
APA Yan, Y,Guo, S,Xiong, W,Huang, JB,Li, ZC,&Ma, JM.(2005).Molecular arrangement and recognition of a new bolaform cinnamic acid derivative in LB films.ACTA PHYSICO-CHIMICA SINICA,21(5),550-555.
MLA Yan, Y,et al."Molecular arrangement and recognition of a new bolaform cinnamic acid derivative in LB films".ACTA PHYSICO-CHIMICA SINICA 21.5(2005):550-555.

入库方式: OAI收割

来源:化学研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。