A novel hybrid crystal of chiral racemic complexes coexisting with two kinds of polyoxomolybdates: synthesis and structure of [Co(bPY)(3)](2)[Mo6O19] [beta-(H2Mo8O26)] center dot 4H(2)O
文献类型：期刊论文
| 作者 | Wang, WJ; Xu, L; Wei, YG; Li, FY; Gao, GG; Wang, EB |
| 刊名 | JOURNAL OF SOLID STATE CHEMISTRY
 |
| 出版日期 | 2005-03-01 |
| 卷号 | 178期号:3页码:608-612 |
| 关键词 | Hydrothermal Synthesis Racemic Complexes Polyoxometalates Octamolybdate Crystal Structure |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2004.11.034 |
| 英文摘要 | A novel polyoxometalate-based organic-inorganic hybrid compound, [Co(bpy)(3)](2) [Mo6O19] [beta-(H2Mo8O26)] center dot 4H(2)O (1), have been hydrothermally synthesized and structurally characterized by elemental analysis, single-crystal X-ray diffraction, IR and X-ray photoelectron spectra. Compound 1 represents the first example that racemic complexes coexisting with two kinds of polyoxomolybdate anions in the same crystal architecture, which should be of rare chance that four kinds of complexes crystallizes into a compound. (c) 2005 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000227920000002 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/56907]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xu, L |
| 作者单位 | 1.NE Normal Univ, Dept Chem, Changchun 130024, Jilin Province, Peoples R China 2.Baicheng Teachers Coll, Dept Chem, Baicheng 137000, Peoples R China 3.Peking Univ, Coll Chem & Mol Engn, Unstable & Stable Species Inst Phys Chem, State Key Lab Struct Chem, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, WJ,Xu, L,Wei, YG,et al. A novel hybrid crystal of chiral racemic complexes coexisting with two kinds of polyoxomolybdates: synthesis and structure of [Co(bPY)(3)](2)[Mo6O19] [beta-(H2Mo8O26)] center dot 4H(2)O[J]. JOURNAL OF SOLID STATE CHEMISTRY,2005,178(3):608-612. |
| APA | Wang, WJ,Xu, L,Wei, YG,Li, FY,Gao, GG,&Wang, EB.(2005).A novel hybrid crystal of chiral racemic complexes coexisting with two kinds of polyoxomolybdates: synthesis and structure of [Co(bPY)(3)](2)[Mo6O19] [beta-(H2Mo8O26)] center dot 4H(2)O.JOURNAL OF SOLID STATE CHEMISTRY,178(3),608-612. |
| MLA | Wang, WJ,et al."A novel hybrid crystal of chiral racemic complexes coexisting with two kinds of polyoxomolybdates: synthesis and structure of [Co(bPY)(3)](2)[Mo6O19] [beta-(H2Mo8O26)] center dot 4H(2)O".JOURNAL OF SOLID STATE CHEMISTRY 178.3(2005):608-612. |
入库方式： OAI收割
来源：化学研究所
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