The role of polymorphic crystal structure and morphology in enzymatic degradation of melt-crystallized poly(butylene adipate) films
文献类型：期刊论文
| 作者 | Gan, ZH; Kuwabara, K; Abe, H; Iwata, T; Doi, Y |
| 刊名 | POLYMER DEGRADATION AND STABILITY
 |
| 出版日期 | 2005 |
| 卷号 | 87期号:1页码:191-199 |
| 关键词 | Crystal Structure Enzymatic Degradation Morphology Polymorphism Spherulites |
| ISSN号 | 0141-3910 |
| DOI | 10.1016/j.polymdegradstab.2004.08.007 |
| 英文摘要 | The enzymatic degradation of melt-crystallized poly(butylene adipate) (PBA) films corresponding to the alpha crystal structure. beta crystal structure, and the two mixed crystal forms were studied by using the lipase from Pseudomonos sp. The results indicate that the degradation of each crystal form depends on its crystal size, while the comparison of degradation between polymorphic crystals indicates that there is no relationship between thermodynamic stability and biodegradability. The films with alpha crystal structure were found to have faster degradation rate than the films with beta crystal structures. although the alpha crystal is a thermodynamically stable phase with larger crystal size. The films with mixed alpha and beta crystal structures showed a lowest degradation rate. In order to study the degradation mechanism, the morphologies of melt-crystallized PBA films before and after enzymatic degradation were studied by means of polarized optical microscopy, scanning electron microscopy (SEM), and atomic force microscopy (AFM). Different spherulite morphologies have been found in the PBA films corresponding to the different crystal structures. The PBA films with mixed alpha and beta crystal structures showed spherulites with banded rings, while the films with either alpha or beta crystal structure slid not show banded spherulites. In addition, the oriented "lines" which are crystalline structures induced by the Teflon films during melt-crystallization were only observed on the film surface with a crystal structure. The influences of surface structure. morphology. and chain mobility of polymorphic crystals were discussed for understanding the role of crystal structure and morphology in determining the biodegradability of polymorphic crystals. (C) 2004 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000225743400025 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/56911]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gan, ZH |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China 2.Riken Inst Phys & Chem Res, JST Corp, SORST Grp, Polymer Chem Lab, Wako, Saitama 3510198, Japan 3.Tokyo Inst Technol, Midori Ku, Dept Innovat & Engineered Mat, Yokohama, Kanagawa 2268502, Japan |
| 推荐引用方式 GB/T 7714 | Gan, ZH,Kuwabara, K,Abe, H,et al. The role of polymorphic crystal structure and morphology in enzymatic degradation of melt-crystallized poly(butylene adipate) films[J]. POLYMER DEGRADATION AND STABILITY,2005,87(1):191-199. |
| APA | Gan, ZH,Kuwabara, K,Abe, H,Iwata, T,&Doi, Y.(2005).The role of polymorphic crystal structure and morphology in enzymatic degradation of melt-crystallized poly(butylene adipate) films.POLYMER DEGRADATION AND STABILITY,87(1),191-199. |
| MLA | Gan, ZH,et al."The role of polymorphic crystal structure and morphology in enzymatic degradation of melt-crystallized poly(butylene adipate) films".POLYMER DEGRADATION AND STABILITY 87.1(2005):191-199. |
入库方式： OAI收割
来源：化学研究所
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