Ethylene polymerization with iron-based diimine catalyst supported on MCM-41
文献类型:期刊论文
作者 | Zhang, MG; Xu, H; Guo, CY; Ma, Z; Dong, JX; Ke, YC; Hu, YL |
刊名 | POLYMER INTERNATIONAL
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出版日期 | 2005-02-01 |
卷号 | 54期号:2页码:274-278 |
关键词 | Mcm-41 Iron-based Diimine Catalyst Supported Catalyst Ethylene Polymerization |
ISSN号 | 0959-8103 |
DOI | 10.1002/pi.1667 |
英文摘要 | A mesoporous molecular sieve MCM-41 supported iron-based diimine catalyst (MC) was prepared for the first time. The kinetic behavior of ethylene polymerization with MC was studied. The effects of Al/Fe molar ratio and various cocatalysts on the catalytic activity and properties of the polyethylene obtained were investigated. The results showed that good catalytic activities can be reached with cocatalyst methylaluminoxane (MAO) and triethylaluminium (TEA). Ethylene polymerization with MC gave polymers with higher molecular weight, melting temperature and onset temperatures of decomposition (T-onset) and better morphology than those obtained with the corresponding homogeneous catalyst. (C) 2004 Society of Chemical Industry. |
语种 | 英语 |
WOS记录号 | WOS:000226731900006 |
出版者 | JOHN WILEY & SONS LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/56919] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Hu, YL |
作者单位 | 1.Chinese Acad Sci, Key Lab Engn Phys, Inst Chem, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Chinese Acad Sci, State Key Lab Coal Convers, Inst Coal Chem, Taiyuan 030001, Peoples R China 4.Taiyuan Univ Technol, Inst Special Chem, Taiyuan 030024, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, MG,Xu, H,Guo, CY,et al. Ethylene polymerization with iron-based diimine catalyst supported on MCM-41[J]. POLYMER INTERNATIONAL,2005,54(2):274-278. |
APA | Zhang, MG.,Xu, H.,Guo, CY.,Ma, Z.,Dong, JX.,...&Hu, YL.(2005).Ethylene polymerization with iron-based diimine catalyst supported on MCM-41.POLYMER INTERNATIONAL,54(2),274-278. |
MLA | Zhang, MG,et al."Ethylene polymerization with iron-based diimine catalyst supported on MCM-41".POLYMER INTERNATIONAL 54.2(2005):274-278. |
入库方式: OAI收割
来源:化学研究所
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