中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Ethylene polymerization with iron-based diimine catalyst supported on MCM-41

文献类型:期刊论文

作者Zhang, MG; Xu, H; Guo, CY; Ma, Z; Dong, JX; Ke, YC; Hu, YL
刊名POLYMER INTERNATIONAL
出版日期2005-02-01
卷号54期号:2页码:274-278
关键词Mcm-41 Iron-based Diimine Catalyst Supported Catalyst Ethylene Polymerization
ISSN号0959-8103
DOI10.1002/pi.1667
英文摘要A mesoporous molecular sieve MCM-41 supported iron-based diimine catalyst (MC) was prepared for the first time. The kinetic behavior of ethylene polymerization with MC was studied. The effects of Al/Fe molar ratio and various cocatalysts on the catalytic activity and properties of the polyethylene obtained were investigated. The results showed that good catalytic activities can be reached with cocatalyst methylaluminoxane (MAO) and triethylaluminium (TEA). Ethylene polymerization with MC gave polymers with higher molecular weight, melting temperature and onset temperatures of decomposition (T-onset) and better morphology than those obtained with the corresponding homogeneous catalyst. (C) 2004 Society of Chemical Industry.
语种英语
WOS记录号WOS:000226731900006
出版者JOHN WILEY & SONS LTD
源URL[http://ir.iccas.ac.cn/handle/121111/56919]  
专题中国科学院化学研究所
通讯作者Hu, YL
作者单位1.Chinese Acad Sci, Key Lab Engn Phys, Inst Chem, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
3.Chinese Acad Sci, State Key Lab Coal Convers, Inst Coal Chem, Taiyuan 030001, Peoples R China
4.Taiyuan Univ Technol, Inst Special Chem, Taiyuan 030024, Peoples R China
推荐引用方式
GB/T 7714
Zhang, MG,Xu, H,Guo, CY,et al. Ethylene polymerization with iron-based diimine catalyst supported on MCM-41[J]. POLYMER INTERNATIONAL,2005,54(2):274-278.
APA Zhang, MG.,Xu, H.,Guo, CY.,Ma, Z.,Dong, JX.,...&Hu, YL.(2005).Ethylene polymerization with iron-based diimine catalyst supported on MCM-41.POLYMER INTERNATIONAL,54(2),274-278.
MLA Zhang, MG,et al."Ethylene polymerization with iron-based diimine catalyst supported on MCM-41".POLYMER INTERNATIONAL 54.2(2005):274-278.

入库方式: OAI收割

来源:化学研究所

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